A sodium trifluoromethanesulfinate-mediated photocatalytic strategy for aerobic oxidation of alcohols

被引：36
作者：
Zhu, Xianjin [1 ]
Liu, Can [1 ]
Liu, Yong [1 ]
Yang, Haijun [1 ]
Fu, Hua [1 ]
机构：
[1] Tsinghua Univ, Minist Educ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 82期
基金：
国家重点研发计划; 中国国家自然科学基金;
关键词：
VISIBLE-LIGHT PHOTOCATALYSIS; PHOTOREDOX CATALYSIS; SELECTIVE OXIDATION; EFFICIENT OXIDATION; CARBONYL-COMPOUNDS; MOLECULAR-OXYGEN; ORGANOCATALYSIS; COMPLEXES; KETONES; TIO2;
D O I：
10.1039/d0cc05799a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A sodium trifluoromethanesulfinate-mediated photocatalytic strategy for the aerobic oxidation of alcohols has been developed for the first time, and the photoredox aerobic oxidation of secondary and primary alcohols provided the corresponding ketones and carboxylic acids, respectively, in high to excellent yields.
引用
收藏
页码：12443 / 12446
页数：4
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