Thermal expansion behaviour of high melting point oxides

The thermal expansion characteristics of the reinforcement and matrix constituents in ceramic composites have a strong influence on a number of aspects of the composite performance. Thus the toughness and strength of the composite can be influenced by local residual stresses due to the thermal expansion mismatch of different phases. Moreover, in individual polycrystalline phases, local stress variations from grain to grain, generated as a result of anisotropy of thermal expansion in combination with anisotropy of elasticity can influence strength and toughness in similar ways. In the present study, reported data on the thermal expansion coefficients of oxides having potential as constituents in high temperature composites are reviewed and complemented with additional measurements made using high temperature X-ray diffraction.