Nanobiocatalysis in Organic Media: Opportunities for Enzymes in Nanostructures

被引:35
作者
Ge, Jun [1 ]
Yang, Cheng [1 ]
Zhu, Jingying [1 ]
Lu, Diannan [1 ]
Liu, Zheng [1 ]
机构
[1] Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
Biocatalysis; Catalytic activity; Industrial enzymes; Nanomaterials; Organic media; Pharmaceutical intermediates; POLYETHYLENE-GLYCOL; CARBON NANOTUBES; SINGLE-ENZYME; POLYMER; PROTEIN; LIPASE; STABILITY; NANOGEL; BIOCATALYSIS; STREPTAVIDIN;
D O I
10.1007/s11244-012-9906-z
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this review, we emphasized the importance of enzymatic processes in organic media, summarized recent advances of nanobiocatalysts with high activities in organic media, and proposed three general principles for designing nanobiocatalysis therein: facilitated substrate transport, retention of protein structure, and highly dispersed catalyst forms.
引用
收藏
页码:1070 / 1080
页数:11
相关论文
共 79 条
[1]   Directed assembly of carbon nanotubes at liquid-liquid interfaces: Nanoscale conveyors for interfacial biocatalysis [J].
Asuri, P ;
Karajanagi, SS ;
Dordick, JS ;
Kane, RS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (04) :1046-1047
[2]   Covalently incorporated protein-nanogels using AGET ATRP in an inverse miniemulsion [J].
Averick, Saadyah E. ;
Magenau, Andrew J. D. ;
Simakova, Antonina ;
Woodman, Bradley F. ;
Seong, Andrew ;
Mehl, Ryan A. ;
Matyjaszewski, Krzysztof .
POLYMER CHEMISTRY, 2011, 2 (07) :1476-1478
[3]   SYNTHESIS OF FATTY ESTERS BY POLYETHYLENE GLYCOL-MODIFIED LIPASE [J].
BASRI, M ;
AMPON, K ;
ZIN, WM ;
YUNUS, W ;
RAZAK, CNA ;
SALLEH, AB .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 1995, 64 (01) :10-16
[4]   Well-defined protein-polymer conjugates via in situ RAFT polymerization [J].
Boyer, Cyrille ;
Bulmus, Volga ;
Liu, Jingquan ;
Davis, Thomas P. ;
Stenzel, Martina H. ;
Barner-Kowollik, Christopher .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (22) :7145-7154
[5]   Industrial methods for the production of optically active intermediates [J].
Breuer, M ;
Ditrich, K ;
Habicher, T ;
Hauer, B ;
Kesseler, M ;
Stürmer, R ;
Zelinski, T .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (07) :788-824
[6]   Site-specific polymer-streptavidin bioconjugate for pH-controlled binding and triggered release of biotin [J].
Bulmus, V ;
Ding, ZL ;
Long, CJ ;
Stayton, PS ;
Hoffman, AS .
BIOCONJUGATE CHEMISTRY, 2000, 11 (01) :78-83
[7]  
Carrea G, 2000, ANGEW CHEM INT EDIT, V39, P2226
[8]   Effect of PEG modification on subtilisin Carlsberg activity, enantioselectivity, and structural dynamics in 1,4-dioxane [J].
Castillo, Betzaida ;
Sola, Ricardo J. ;
Ferrer, Amaris ;
Barletta, Gabriel ;
Griebenow, Kai .
BIOTECHNOLOGY AND BIOENGINEERING, 2008, 99 (01) :9-17
[9]   SITE-SPECIFIC CONJUGATION OF A TEMPERATURE-SENSITIVE POLYMER TO A GENETICALLY-ENGINEERED PROTEIN [J].
CHILKOTI, A ;
CHEN, GH ;
STAYTON, PS ;
HOFFMAN, AS .
BIOCONJUGATE CHEMISTRY, 1994, 5 (06) :504-507
[10]   Performance evaluation of hyperbranched aramids as potential supports for protein immobilization [J].
Cosulich, ME ;
Russo, S ;
Pasquale, S ;
Mariani, A .
POLYMER, 2000, 41 (13) :4951-4956