Chiral recognition in aggregation of gold nanoparticles grafted with helicenes

被引:18
作者
An, Zengjian [1 ]
Yamaguchi, Masahiko [1 ]
机构
[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan
关键词
D O I
10.1039/c2cc32735j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chiral recognition was observed in the interactions of gold nanoparticles grafted with (+/-)-, (M)-, and (P)-helicenethiol. Although the nanoparticles contain equal enantiomeric excess, a 1 : 1 mixture of (M)- and (P)-nanoparticles aggregated more rapidly in solution than (+/-)-nanoparticles.
引用
收藏
页码:7383 / 7385
页数:3
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