Recycling of WC-Co from scrap materials

被引:10
作者
Sampath, A [1 ]
Sudarshan, TS [1 ]
机构
[1] Mat Modificat Inc, Fairfax, VA 22031 USA
关键词
Cobalt - Compaction - Cutting tools - Electrodeposition - Mechanical variables measurement - Microhardness - Nanostructured materials - Particle size analysis - Recycling - Tungsten carbide - X ray diffraction analysis;
D O I
10.1179/003258902225001588
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
WC-Co scrap generated by the cutting tool industries was electrochemically broken down to cobalt, which was deposited at the cathode and a mixture of tungsten oxide and tungstic acid was collected at the anode with an overall recovery efficiency of about 90%. The tungsten oxide/tungstic acid was reduced to produce nanostructural tungsten powders, which were subsequently carburised and chemically coated with cobalt to produce WC-Co powders. The powders synthesised were characterised for purity and size. The WC-Co powders, thus obtained were consolidated to near theoretical densities using a novel plasma pressure compaction ((PC)-C-2) technique. The microhardness of the consolidated sample was measured to be 2200 HV, which is 20% higher than the reported literature values. (C) 2002 IoM Communications Ltd.
引用
收藏
页码:21 / 24
页数:4
相关论文
共 8 条
[1]  
*ASM INT, ASM HDB, V7, P935
[2]  
*C RIV ASS INC, 1992, TUNGST WORLD MARK SU
[3]  
GHANDEHARI MH, 1980, J ELECTROCHEM SOC, V127, P2144, DOI 10.1149/1.2129361
[4]  
KIEFFER BF, 1986, R HM, P65
[5]  
KIELTY ER, 1998, E MJ MAR, P38
[6]  
LATHA TM, 1989, HYDROMETALLURGY, V22, P353
[7]  
SRINIVASAN GN, 1992, T POWDER METALL ASS, V19, P90
[8]  
1998, COBALT NEWS, V98, P9