Efficient Synthesis of Substituted Cyclic α-Aminophosphonates

被引：28

作者：

Odinets, Irina L. ^{[1
]}

Artyushin, Oleg I. ^{[1
]}

Shevchenko, Nikolay ^{[2
]}

Petrovskii, Pavel V. ^{[1
]}

Nenajdenko, Valentin G. ^{[2
]}

Roeschenthaler, Gerd-Volker ^{[3
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Moscow 119992, Russia

[3] Univ Bremen, Inst Inorgan & Phys Chem, D-28334 Bremen, Germany

来源：

SYNTHESIS-STUTTGART | 2009年 / 04期

关键词：

diethyl phosphonate; cyclic imines; addition reactions; alpha-aminophosphonates; ASYMMETRIC-SYNTHESIS; AZIRIDINE; 2-PHOSPHONATES; ACIDS; ANALOGS; DERIVATIVES; INHIBITORS; CRYSTAL; IMINES; ESTERS; ROUTE;

D O I：

10.1055/s-0028-1083349

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of diethyl phosphite to cyclic imines bearing alkyl, aryl, or heteroaryl substituents at the alpha-position in diethyl ether at room temperature presents an efficient route to substituted cyclic alpha-aminophosphonates. The application of boron trifluoride diethyl ether complex as a catalyst significantly accelerates the reaction.

引用

页码：577 / 582

页数：6

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