Particle redistribution during dendritic solidification of particle suspensions

被引:91
作者
Shanti, Noah O. [1 ]
Araki, Kiyoshi [1 ]
Halloran, John W. [1 ]
机构
[1] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA
关键词
D O I
10.1111/j.1551-2916.2006.01094.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Solidification of the liquid medium in ceramic suspensions containing less than a critical volume fraction powder leads to the formation of particle-free dendrites of the frozen medium. These particle-free dendrites create, after sublimation of the frozen vehicle, large dendrite pores. We define the conditions under which particle-free dendrites form, and relate the size and volume fraction of the dendrites to the volume fraction powder and the solidification rate.
引用
收藏
页码:2444 / 2447
页数:4
相关论文
共 17 条
[1]  
Araki K, 2004, J AM CERAM SOC, V87, P1859
[2]   Porous ceramic bodies with interconnected pore channels by a novel freeze casting technique [J].
Araki, K ;
Halloran, JW .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (05) :1108-1114
[3]  
ARAKI K, 2004, THESIS U MICHIGAN
[4]   Solid-liquid interfacial energy of camphene [J].
Bayender, B ;
Marasli, N ;
Cadirli, E ;
Gündüz, M .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1999, 270 (02) :343-348
[5]  
BILONI H, 1983, PHYS METALLURGY, P500
[6]   EQUATION OF STATE FOR NONATTRACTING RIGID SPHERES [J].
CARNAHAN, NF ;
STARLING, KE .
JOURNAL OF CHEMICAL PHYSICS, 1969, 51 (02) :635-&
[7]   Freezing as a path to build complex composites [J].
Deville, S ;
Saiz, E ;
Nalla, RK ;
Tomsia, AP .
SCIENCE, 2006, 311 (5760) :515-518
[8]   Synthesis of porous ceramics with complex pore structure by freeze-dry processing [J].
Fukasawa, T ;
Ando, M ;
Ohji, T ;
Kanzaki, S .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2001, 84 (01) :230-232
[9]   Aggregation effects on the compressive flow properties and drying behavior of colloidal silica suspensions [J].
Guo, JJ ;
Lewis, JA .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1999, 82 (09) :2345-2358
[10]   Evolution of porosity by freeze casting and sintering of sol-gel derived ceramics [J].
Koch, D ;
Andresen, L ;
Schmedders, T ;
Grathwohl, G .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2003, 26 (1-3) :149-152