New Scandium-containing Coordination Polymers with Linear Linker Molecules: Crystal Structures and Luminescence Properties

Two new scandium-containing coordination polymers, with the formulae {(CH3)(2)NH2}[Sc(BPDC)(2)] (1) and [Sc(OH) (BPyDC)] (2) were solvothermally synthesized by using the linear linker molecules biphenyl-4,4'-dicarboxylic acid (H2BPDC) and 2,2'-bipyridine-5,5'-dicarboxylic acid (H2BPyDC). Crystal structures were determined from single-crystal and powder X-ray diffraction data, respectively. The crystal structures of1and2contain isolated ScO(6)or chains oftranscorner-sharing ScO(6)octahedra as the inorganic building unit (IBU), which are connected by the linker molecules to a 3D framework or a layered structure, respectively. The compounds were characterized by IR-spectroscopy, elemental analysis, thermogravimetric analysis and photoluminescence spectroscopy.1shows blue emission at 400 nm, while2exhibits intense green emission at 550 nm with a high quantum yield (QY) of 69 %.