Supramolecular Encapsulated Rhodium Catalysts for Branched Selective Hydroformylation of Alkenes at High Temperature

被引：41

作者：

Besset, Tatiana ^{[1
]}

Norman, David W. ^{[2
]}

Reek, Joost N. H. ^{[1
]}

机构：

[1] Univ Amsterdam, vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands

[2] Eastman Chem Co, Kingsport, TN 37662 USA

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 2-3期

关键词：

high temperature processes; high-pressure infrared spectroscopy (HP-IR); hydroformylation; regioselectivity; supramolecular assembly; REGIOSELECTIVE HYDROFORMYLATION; PHOSPHORUS LIGANDS; BIDENTATE LIGANDS; HOMOGENEOUS CATALYSIS; HIGH-THROUGHPUT; HYDROGENATION; CHEMISTRY; LIBRARIES; ALDEHYDES; COMPLEX;

D O I：

10.1002/adsc.201200790

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This study reveals that, in contrast to expectations, supramolecular encapsulated rhodium catalysts can be used at industrially relevant temperatures (7580 degrees C), providing highly active catalysts. The unprecedented regioselectivity for the branched aldehydes can be retained if high carbon monoxide (CO) concentrations are used.

引用

页码：348 / 352

页数：5

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