Rhodium(I) complexes of a PBP ambiphilic ligand:: Evidence for a metal → borane interaction

被引：188
作者：
Bontemps, SB
Gornitzka, H
Bouhadir, G
Miqueu, K
Bourissou, D
机构：
[1] Univ Toulouse 3, Lab Heterochim Fondamentale & Appl, CNRS, UMR 5069, F-31062 Toulouse 09, France
[2] Lab Chim Theor & Phys Chim Mol, UMR 5624, F-64013 Pau, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 10期
关键词：
sigma-acceptor ligands; ab initio calculations; boranes; phosphanes; rhodium;
D O I：
10.1002/anie.200503649
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
To and fro: Diphosphanylborane derivative 1 behaves as a tridentate, ambiphilic ligand towards rhodium(I) fragments (see picture). The presence of metal-→borane interactions in the resulting square-pyramidal complexes is highlighted by structural analyses and DFT calculations. (Chemical Equation Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：1611 / 1614
页数：4
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