Rheological properties of water-salt solutions of polyethylene glycols of various molecular masses in the range of 293.15 to 323.15 K

被引:4
|
作者
Shulyak, I. V. [1 ]
Grushova, E. I. [1 ]
机构
[1] Belarus State Technol Univ, Minsk 220050, BELARUS
关键词
polyethylene glycol; water-salt solution; intrinsic viscosity; conformation of macromolecules; AQUEOUS-SOLUTIONS;
D O I
10.1134/S0036024413030291
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dependences of the kinematic viscosity of water-salt solutions of polyethylene glycols (PEGs) of various molecular masses are studied. The intrinsic viscosity, the Huggins and Mark-Kuhn-Houwink constants, and the apparent activation energy of a viscous flow of water-salt solutions of PEGs are determined. The effect of temperature and the salt background on the state of PEG molecules in solution is shown.
引用
收藏
页码:433 / 436
页数:4
相关论文
共 9 条
  • [1] Rheological properties of water-salt solutions of polyethylene glycols of various molecular masses in the range of 293.15 to 323.15 K
    I. V. Shulyak
    E. I. Grushova
    Russian Journal of Physical Chemistry A, 2013, 87 : 433 - 436
  • [2] Rheological properties of aqueous solutions of polyethylene glycols with various molecular weights
    I. V. Shulyak
    E. I. Grushova
    A. M. Semenchenko
    Russian Journal of Physical Chemistry A, 2011, 85 : 419 - 422
  • [3] Rheological properties of aqueous solutions of polyethylene glycols with various molecular weights
    Shulyak, I. V.
    Grushova, E. I.
    Semenchenko, A. M.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 85 (03) : 419 - 422
  • [4] Rheological properties of water-salt solutions of alkaline hydrolysis products of a nitron D polyacrylonitrile fiber
    Krul', LP
    Brazhnikov, MM
    Grinyuk, EV
    Krakodeev, DV
    Rybak, AS
    POLYMER SCIENCE SERIES B, 2003, 45 (3-4) : 85 - 88
  • [5] Rheological properties of water-salt solutions of alkaline hydrolysis products of a nitron D polyacrylonitrile fiber
    Krul', L.P.
    Brazhnikov, M.M.
    Grinyuk, E.V.
    Krakodeev, D.V.
    Rybak, A.S.
    2003, MAIK Nauka (45):
  • [6] Studies of Viscosity Coefficient and Expansivity Properties of Aqueous Solutions of Ethylene Glycol and Polyethylene Glycols at 293.15, 298.15 and 303.15 K and at Ambient Pressure
    Pankaj D. Patil
    Vasim R. Shaikh
    Gaurav R. Gupta
    Dilip G. Hundiwale
    Amulrao U. Borse
    Kesharsingh J. Patil
    Journal of Solution Chemistry, 2016, 45 : 947 - 969
  • [7] Studies of Viscosity Coefficient and Expansivity Properties of Aqueous Solutions of Ethylene Glycol and Polyethylene Glycols at 293.15, 298.15 and 303.15 K and at Ambient Pressure
    Patil, Pankaj D.
    Shaikh, Vasim R.
    Gupta, Gaurav R.
    Hundiwale, Dilip G.
    Borse, Amulrao U.
    Patil, Kesharsingh J.
    JOURNAL OF SOLUTION CHEMISTRY, 2016, 45 (06) : 947 - 969
  • [8] Volumetric and transport properties of ternary solutions of L-serine and L-valine in aqueous NaCl solutions in the temperature range (293.15-323.15) K
    Brinzei, Mihaela
    Ciocirlan, Oana
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2021, 154
  • [9] Rheological properties of reversible thermo-setting in situ gelling solutions with the methylcellulose-polyethylene glycol-citric acid ternary system (2): Effects of various water-soluble polymers and salts on the gelling temperature
    Shimokawa, Ken-ichi
    Saegusa, Katsuhiko
    Ishii, Fumiyoshi
    COLLOIDS AND SURFACES B-BIOINTERFACES, 2009, 74 (01) : 56 - 58