In situ preparation of highly fluorescent pyrene-dyes from non-luminous precursors upon photoirradiation

被引:15
作者
Aotake, Tatsuya [1 ]
Tanimoto, Hiroshi [2 ]
Hotta, Hidekatsu [2 ]
Kuzuhara, Daiki [1 ]
Okujima, Tetsuo [2 ]
Uno, Hidemitsu [2 ]
Yamada, Hiroko [1 ,3 ]
机构
[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Ikoma 6300192, Japan
[2] Ehime Univ, Dept Biol & Chem, Grad Sch Sci & Engn, Matsuyama, Ehime 7908577, Japan
[3] JST, CREST, Chiyoda Ku, Tokyo 1020076, Japan
关键词
PHOTOCHEMICAL-SYNTHESIS; CHEMISTRY;
D O I
10.1039/c3cc40827b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The non-luminous precursor, 2-(1-pyrenyl)-9,10-dihydro-9,10-ethanoanthracene-11,12-dione, was photochemically converted to highly-fluorescent 2-(1-pyrenyl) anthracene quantitatively in solution and in the PMMA film and the fluorescence quantum yield of the acene in benzonitrile was as high as 0.99.
引用
收藏
页码:3661 / 3663
页数:3
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