2-(mesitylmethylsulfanyl) pyridine N-oxide monohydrate

被引：1

作者：

Nayagam, B. Ravindran Durai ^{[1
]}

Jebas, Samuel Robinson ^{[2
]}

Jeyakumar, H. Johnson ^{[3
]}

Schollmeyer, Dieter ^{[4
]}

机构：

[1] Popes Coll, Dept Chem, Sawyerpuram 628251, Tamil Nadu, India

[2] Karunya Univ, Dept Phys, Coimbatore 64114, Tamil Nadu, India

[3] Popes Coll, Dept Phys, Sawyerpuram 628251, Tamil Nadu, India

[4] Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808029255

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C15H17NOS center dot H2O, the benzene and pyridine rings form a dihedral angle of 71.18 (2)degrees. The intramolecular S center dot center dot center dot O distance [2.737 (3) angstrom] is shorter than expected and, in terms of hybridization principles, the N-C-S angle [114.1 (2)degrees] is smaller than expected. The crystal structure is stabilized by intermolecular O-H center dot center dot center dot O and weak C-H center dot center dot center dot O hydrogen bonds. In addition, weak pi-pi stacking interactions with a centroid - centroid distance of 3.778 (3) angstrom are also observed.

引用

页码：O1952 / U4014

页数：10

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