2-(mesitylmethylsulfanyl) pyridine N-oxide monohydrate

被引:1
|
作者
Nayagam, B. Ravindran Durai [1 ]
Jebas, Samuel Robinson [2 ]
Jeyakumar, H. Johnson [3 ]
Schollmeyer, Dieter [4 ]
机构
[1] Popes Coll, Dept Chem, Sawyerpuram 628251, Tamil Nadu, India
[2] Karunya Univ, Dept Phys, Coimbatore 64114, Tamil Nadu, India
[3] Popes Coll, Dept Phys, Sawyerpuram 628251, Tamil Nadu, India
[4] Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany
关键词
D O I
10.1107/S1600536808029255
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C15H17NOS center dot H2O, the benzene and pyridine rings form a dihedral angle of 71.18 (2)degrees. The intramolecular S center dot center dot center dot O distance [2.737 (3) angstrom] is shorter than expected and, in terms of hybridization principles, the N-C-S angle [114.1 (2)degrees] is smaller than expected. The crystal structure is stabilized by intermolecular O-H center dot center dot center dot O and weak C-H center dot center dot center dot O hydrogen bonds. In addition, weak pi-pi stacking interactions with a centroid - centroid distance of 3.778 (3) angstrom are also observed.
引用
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页码:O1952 / U4014
页数:10
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