Water stable triazolyl phosphonate MOFs: steep water uptake and facile regeneration

被引：29

作者：

Begum, S. ^{[1
,2
]}

Horike, S. ^{[2
]}

Kitagawa, S. ^{[2
,3
]}

Krautscheid, H. ^{[1
]}

机构：

[1] Univ Leipzig, Fak Chem & Mineral, D-04103 Leipzig, Germany

[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[3] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Sakyo Ku, Kyoto 6068501, Japan

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 43期

关键词：

METAL-ORGANIC FRAMEWORK; ADSORPTION; COORDINATION; STABILITY; SORPTION; VAPOR; PRESSURE; SITES;

D O I：

10.1039/c5dt02651b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new microporous cobalt triazolyl phosphonate MOF (3)(alpha)[Co4L3(mu(3)-OH)(H2O)(3)](SO4)(0.5)center dot xH(2)O (L2- = 4-(4H-1,2,4-triazol-4-yl)-phenyl phosphonate) exhibits exciting features including high water stability, reversible hydration-dehydration, steep water uptake in repeated cycles at low water vapor pressures and reactivation at room temperature under mild evacuation.

引用

页码：18727 / 18730

页数：4

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