Synthesis, characterization, and mesomorphic properties of a mixed [60]fullerene-ferrocene liquid-crystalline dendrimer

被引：92

作者：

Dardel, B ^{[1
]}

Deschenaux, R ^{[1
]}

Even, M ^{[1
]}

Serrano, E ^{[1
]}

机构：

[1] Univ Neuchatel, Inst Chim, CH-2000 Neuchatel, Switzerland

来源：

MACROMOLECULES | 1999年 / 32卷 / 16期

关键词：

D O I：

10.1021/ma990034v

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Addition reaction of the malonate-based second-generation ferrocene-containing liquid-crystalline dendrimer 16 to [60]fullerene led to the title compound 1. Molecule 1 showed good solubility in common organic solvents and good thermal stability. Examination of its mesomorphic properties revealed the presence of an enantiotropic smectic A phase, which was identified by polarized optical microscopy from the observation of typical focal-conic and homeotropic textures. The dendritic addend 16 exhibited similar properties as those of the fullerene-based dendrimer. The results described in this report open the way to the elaboration of fullerene-containing liquid-crystalline macromolecules.

引用

页码：5193 / 5198

页数：6

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