Light scattering enhancement in an aqueous solution of spermine-induced fractal J-aggregate composite -: art. no. 050401

被引:21
作者
Micali, N
Villari, V
Scolaro, LM
Romeo, A
Castriciano, MA
机构
[1] CNR, Ist Proc Chimicofis, Sez Messina, I-98123 Messina, Italy
[2] Univ Messina Salita Sperone 31, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy
来源
PHYSICAL REVIEW E | 2005年 / 72卷 / 05期
关键词
D O I
10.1103/PhysRevE.72.050401
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We performed an experimental investigation on the scattering and extinction properties of an aqueous solution of spermine-induced fractal J aggregates, constituted by porphyrin molecules. In analogy with nanostructured particle composites, the dipolar moments of different porphyrins, not belonging to the J aggregates, are coupled and generate a strong light scattering enhancement. Both the enhanced scattered intensity and the imaginary part of the polarizability of the system obey scaling laws with the optical spectral dimension d(0)=0.3.
引用
收藏
页数:4
相关论文
共 30 条
[1]   Linear absorption as a tool to measure the exciton delocalization length in molecular assemblies [J].
Bakalis, LD ;
Knoester, J .
JOURNAL OF LUMINESCENCE, 2000, 87-9 (87) :66-70
[2]  
Bohren C.F., 1998, ABSORPTION SCATTERIN
[3]   Direct observation of localized second-harmonic enhancement in random metal nanostructures [J].
Bozhevolnyi, SI ;
Beermann, J ;
Coello, V .
PHYSICAL REVIEW LETTERS, 2003, 90 (19) :4
[4]   Direct observation of localized dipolar excitations on rough nanostructured surfaces [J].
Bozhevolnyi, SI ;
Markel, VA ;
Coello, V ;
Kim, W ;
Shalaev, VM .
PHYSICAL REVIEW B, 1998, 58 (17) :11441-11448
[5]   Nanosized porphyrin J-aggregates in water/AOT/decane microemulsions [J].
Castriciano, MA ;
Romeo, A ;
Villari, V ;
Micali, N ;
Scolaro, LM .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (26) :9054-9059
[6]   STRUCTURE AND FRACTAL DIMENSION OF PROTEIN-DETERGENT COMPLEXES [J].
CHEN, SH ;
TEIXEIRA, J .
PHYSICAL REVIEW LETTERS, 1986, 57 (20) :2583-2586
[7]   COMPARISON OF A FRACTAL SMOKE OPTICS MODEL WITH LIGHT EXTINCTION MEASUREMENTS [J].
DOBBINS, RA ;
MULHOLLAND, GW ;
BRYNER, NP .
ATMOSPHERIC ENVIRONMENT, 1994, 28 (05) :889-897
[8]   Low-threshold lasing and broad-band multiphoton-excited light emission from Ag aggregate-adsorbate complexes in microcavity [J].
Drachev, VP ;
Kim, WT ;
Safonov, VP ;
Podolskiy, VA ;
Zakovryashin, NS ;
Khaliullin, EN ;
Shalaev, VM ;
Armstrong, RL .
JOURNAL OF MODERN OPTICS, 2002, 49 (3-4) :645-662
[9]   The optical dynamics of excitons in cylindrical J-aggregates [J].
Lampoura, SS ;
Spitz, C ;
Dähne, S ;
Knoester, J ;
Duppen, K .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (12) :3103-3111
[10]   Experimental evidence for self-similar structures in the aggregation of porphyrins in aqueous solutions [J].
Mallamace, F ;
Micali, N ;
Trusso, S ;
Scolaro, LM ;
Romeo, A ;
Terracina, A ;
Pasternack, RF .
PHYSICAL REVIEW LETTERS, 1996, 76 (25) :4741-4744