Vibrational evidence for a percolative behavior in Zn1-xBexSe -: art. no. 035213

被引:41
作者
Pagès, O
Ajjoun, M
Bormann, D
Chauvet, C
Tournié, E
Faurie, JP
机构
[1] Inst Phys, F-57078 Metz, France
[2] Lab Physicochim Interfaces & Applicat, F-62037 Lens, France
[3] Ctr Rech Heteroepitaxie & Ses Applicat, F-06560 Valbonne, France
关键词
D O I
10.1103/PhysRevB.65.035213
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present an atypical multimode behavior in the Raman spectra recorded with Zn1-xBexSe, which belongs to the new class of ternary semiconductor alloys made of materials with highly contrasted bond stiffness. We observe the activation of a strong extra BeSe-like optical mode for x between the percolation thresholds of the Be-Se and Zn-Se bonds. This extra mode is attributed to Be-Se bonds within the quasicontinuous Be-rich hardlike cluster that forms above the percolation threshold. Our observations can be quantitatively explained in terms of a generalized version of the standard modified-random-element-isodisplacement model.
引用
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页码:1 / 6
页数:6
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