A comparison on the structural and optical properties of different rare earth doped phosphate glasses

被引:10
|
作者
Deepa, A., V [1 ]
Murugasen, Priya [2 ]
Muralimanohar, P. [2 ]
Sathyamoorthy, K. [2 ]
Vinothkumar, P. [2 ]
机构
[1] Bharathiyar Univ, R&D Ctr, Coimbatore, Tamil Nadu, India
[2] Saveetha Engn Coll, Dept Phys, Chennai, Tamil Nadu, India
来源
OPTIK | 2019年 / 181卷
关键词
Glass; FTIR; X-ray diffraction analysis; Rare earth elements; Fluorescence; SAMARIUM;
D O I
10.1016/j.ijleo.2018.12.045
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Phosphate glasses with different RE element dopants were prepared by conventional melt quenching method. Dopants like Nd2O3, Sm2O3 and Eu2O3 were added in glass with 0.5% & 1.5% molar ratio. While varying dopant ratio, phosphate glasses exhibits different properties. The XRD characterization reveals the non-crystallinity of the samples. Both FTIR and Raman confine the ionic nature of the samples. The fluorescence emission spectra Nd2O3 shows that the most intense band occurred at 380 nm due to D-4(712) - I-4(3/2) transition but for Sm2O3 and Eu2O3 most intense bands are seen at 375 nm and 379 nm due to the transition (4) D-1/2 -> H-6(5/2) and of (5)G(5) - F-7(0) respectively.
引用
收藏
页码:361 / 367
页数:7
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