Investigation of Electrochemical Studies of Magnesium Ion Conducting Poly(vinyl alcohol)-Poly(vinyl pyrrolidone) Based Blend Polymers

被引：29

作者：

Jeyabanu, K. ^{[1
]}

Siva, V. ^{[1
]}

Nallamuthu, N. ^{[1
]}

Selvanayagam, S. ^{[2
]}

Bahadur, S. Asath ^{[1
]}

Manikandan, A. ^{[3
]}

机构：

[1] Kalasalingain Univ, Dept Phys, Int Res Ctr, Krishnankoil 626126, India

[2] Govt Arts Coll, Dept Phys, PG & Res, Melur 625106, India

[3] Bharath Univ, Bharath Inst Higher Educ & Res, Dept Chem, Madras 600073, Tamil Nadu, India

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2018年 / 18卷 / 02期

关键词：

PVA; Conductance; Impedance; Polymer; XRD; FTIR; NANOARCHITECTONICS; ELECTROLYTE; TRANSPORT;

D O I：

10.1166/jnn.2018.13969

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polymer blend electrolytes based on magnesium ion conducting PVA-PVP-MgCl2 polymer were prepared at different compositions by solution casting techniques. The prepared films were characterised by various techniques such as XRD and FTIR. Amorphous nature and structural coordination of polymer electrolyte were confirmed by X-ray diffraction and Fourier transform infrared spectroscopy studies. The ionic conductivity of the prepared polymer electrolytes were analysed through ac impedance spectroscopy. The highest conductivity was found to be in the order of similar to 10(-6) Scm(-1) at an ambient temperature for the composition of 50PVA:50PVP: 5 wt% MgCl2. Conductivity versus temperature plot was found to follow an Arrhenius nature. The dielectric behaviour and ionic transport properties of the polymer electrolytes were also analyzed.

引用

页码：1103 / 1109

页数：7

共 37 条

[1] Manifestation of MnCl2 fillers incorporated into the polymer matrices in their dielectric properties [J].

Abdelrazek, E. M. ;

Elashmawi, I. S. ;

Ragab, H. M. .

PHYSICA B-CONDENSED MATTER, 2008, 403 (18) :3097-3104

[2] Catalytic nanoarchitectonics for environmentally compatible energy generation [J].

Abe, Hideki ;

Liu, Jia ;

Ariga, Katsuhiko .

MATERIALS TODAY, 2016, 19 (01) :12-18

[3] THE ACTIVATION ENTROPY FOR TRANSPORT IN IONIC CONDUCTORS [J].

ALMOND, DP ;

WEST, AR .

SOLID STATE IONICS, 1987, 23 (1-2) :27-35

[4] The Way to Nanoarchitectonics and the Way of Nanoarchitectonics [J].

Aono, Masakazu ;

Ariga, Katsuhiko .

ADVANCED MATERIALS, 2016, 28 (06) :989-992

[5] A novel gel electrolyte with lithium difluoro(oxalato)borate salt and Sb2O3 nanoparticles for lithium ion batteries [J].

Aravindan, V. ;

Vickraman, P. .

SOLID STATE SCIENCES, 2007, 9 (11) :1069-1073

[6] What are the emerging concepts and challenges in NANO? Nanoarchitectonics, hand-operating nanotechnology and mechanobiology [J].

Ariga, Katsuhiko ;

Minami, Kosuke ;

Ebara, Mitsuhiro ;

Nakanishi, Jun .

POLYMER JOURNAL, 2016, 48 (04) :371-389

[7] Nanoarchitectonics: a new materials horizon for nanotechnology [J].

Ariga, Katsuhiko ;

Ji, Qingmin ;

Nakanishi, Waka ;

Hill, Jonathan P. ;

Aono, Masakazu .

MATERIALS HORIZONS, 2015, 2 (04) :406-413

[8] POLYMER ELECTROLYTES [J].

ARMAND, MB .

ANNUAL REVIEW OF MATERIALS SCIENCE, 1986, 16 :245-261

[9] A HIGH-RESOLUTION SOLID-STATE NMR AND DSC STUDY OF MISCIBILITY AND CRYSTALLIZATION BEHAVIOR OF POLY(VINYL ALCOHOL)/POLY(N-VINYL-2-PYRROLIDONE) BLENDS [J].

FENG, HQ ;

FENG, ZL ;

SHEN, LF .

POLYMER, 1993, 34 (12) :2516-2519

[10] JUMP RELAXATION IN SOLID ELECTROLYTES [J].

FUNKE, K .

PROGRESS IN SOLID STATE CHEMISTRY, 1993, 22 (02) :111-195

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