Studies on the conducting nanocomposite prepared by polymerization of 2-aminobenzoic acid with aniline from aqueous solutions in montmorillonite

被引：12
作者：
Belmokhtar, A. [1 ]
Benyoucef, A. [1 ]
Zehhaf, A. [1 ]
Yahiaoui, A. [1 ]
Quijada, C. [2 ]
Morallon, E. [3 ,4 ]
机构：
[1] Univ Mascara, Lab Chim Organ Macromol & Mat, Mascara 29000, Algeria
[2] Univ Politecn Valencia, Dept Ingn Text & Papelera, E-03801 Alcoy, Alicante, Spain
[3] Univ Alicante, Dept Quim Fis, E-03080 Alicante, Spain
[4] Univ Alicante, Inst Univ Mat, E-03080 Alicante, Spain
来源：
SYNTHETIC METALS | 2012年 / 162卷 / 21-22期
关键词：
Conducting polymers; Nanocomposites; Intercalation; Exfoliation; Montmorillonite; o-Aminobenzoic acid; Aniline; POLYANILINE-CLAY; INTERCALATION; ENHANCEMENT; POLYMERS; CARBON; LAYERS; XPS;
D O I：
10.1016/j.synthmet.2012.08.014
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A simple and facile method was used to synthesize poly(o-aminobenzoic acid) (PoABA) and polyaniline (PANI) nanocomposites with sodium montmorillonite (M-Na) using in situ intercalative oxidative homo-, and co-polymerization by a substoichiometric amount of ammonium persulfate. The conductive emeraldine salt form of all polymers used is inserted into the layers of M-Na to produce the hybrid with high conductivity. The properties of the hybrid are characterized by X-ray diffraction (XRD), Fourier transform Infrared (FT-IR), thermogravimetric (TG), X-ray photoelectron spectroscopy (XPS), and electrochemical response; the results show that what we obtain is really a nanocomposite. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：1864 / 1870
页数：7
相关论文
共 51 条
[1]  
Abbes I.B., 2010, REACT FUNCT POLYM, V70, P11
[2]  
AKELAH A, 1994, J POLY SC, V55, P153
[3]  
AKELAH A, 1994, NANOSTRUCT MATER, V4, P965
[4]  
Anbarasan R., 2006, INT J POLYMERIC MAT, V55, P803, DOI [10.1080/00914030500496023, DOI 10.1080/00914030500496023]
[5]   POLYANILINE - PROCESSABILITY FROM AQUEOUS-SOLUTIONS AND EFFECT OF WATER-VAPOR ON CONDUCTIVITY [J].
ANGELOPOULOS, M ;
RAY, A ;
MACDIARMID, AG ;
EPSTEIN, AJ .
SYNTHETIC METALS, 1987, 21 (01) :21-30
[6]   Exfoliated nanocomposite from polyaniline graft copolymer/clay [J].
Bae, WJ ;
Kim, KH ;
Jo, WH ;
Park, YH .
MACROMOLECULES, 2004, 37 (26) :9850-9854
[7]   A conducting nanocomposite via intercalative polymerisation of thiophene in montmorillonite clay [J].
Ballav, N ;
Biswas, M .
SYNTHETIC METALS, 2004, 142 (1-3) :309-315
[8]   Preparation and evaluation of composites from montmorillonite and some heterocyclic polymers. 1: Poly(N-vinylcarbazole) montmorillonite nanocomposite system [J].
Biswas, M ;
Ray, SS .
POLYMER, 1998, 39 (25) :6423-6428
[9]  
Biswas M, 2001, ADV POLYM SCI, V155, P167
[10]   Electrochemical behaviour of conducting polymers obtained into clay-catalyst layers.: An in situ Raman spectroscopy study [J].
Boutaleb, N ;
Benyoucef, A ;
Salavagione, HJ ;
Belbachir, M ;
Morallón, E .
EUROPEAN POLYMER JOURNAL, 2006, 42 (04) :733-739
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