Synthesis of a highly enantiomerically enriched silyllithium compound

被引：52

作者：

Strohmann, C ^{[1
]}

Hörnig, J ^{[1
]}

Auer, D ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 07期

关键词：

D O I：

10.1039/b111687h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly enantiomerically enriched silyllithium compound lithiomethylphenyl(1-piperidinylmethyl) silane (4) reacts stereospecifically with chlorosilanes, but over a period of several hours slow racemization in solution at room temperature occurs, which can be supressed by a transmetalation reaction with MgBr2(thf)(4).

引用

页码：766 / 767

页数：2

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