Syntheses, Structures, and Luminescent Properties of the ZnII and CdII 1-D Chain Polymers Assembled by Salicylhydroxamic Acid

被引：1

作者：

Gao Dan-Dan ^{[1
]}

Gao Qian ^{[2
]}

Chen Yan-Mei ^{[2
]}

Li Ya-Hong ^{[2
]}

Li Wu ^{[1
]}

机构：

[1] Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Peoples R China

[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 34卷 / 09期

基金：

中国国家自然科学基金;

关键词：

hydroxamie acids; zinc complex; cadmium complex; 1-D polymeric; CRYSTAL-STRUCTURES; HYDROXAMIC ACIDS; COMPLEXES; COORDINATION; PHOTOLUMINESCENCE; METALLACROWNS; CLEAVAGE; LIGANDS; INHIBITION; TRINUCLEAR;

D O I：

10.14102/j.cnki.0254-5861.2011-0675

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two complexes of compositions [Zn(H(2)shi)(CH3COO)](n) (1) and [Cd(H(2)shi)(2)(H2O)](n), (2) (H(3)shi = salicylhydroxamic acid) have been prepared under solvothermal conditions. They are characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal of 1 belongs to the tetragonal system, space group I4(1)/a with a = 18.972(3), b = 18.972(3), c = 10.938(2) A, V= 3937.1(1) angstrom(3), C9H9NO5Zn, Mr= 276.54, Z= 16, D-c, = 1.866 g/cm(3), mu = 2.500 mm(-1), F(000) = 2240, the final R = 0.0425 and wR = 0.123. The crystal of 2 belongs to the monoclinic system, space group P2/c with a = 16.647(3), b = 6.4577(1), c = 6.5623(1) angstrom, V = 702.4(2) angstrom(3), C14K4Cd2N2O7, M-r= 434.68, Z = 2, D-c= 2.055 g/cm(3), mu = 1.599 mm(-1), F(000) = 432, the final R= 0.0211 and wR = 0.0761. They both possess 1-D polymeric chain structures. The luminescent properties of complexes 1 and 2 have been investigated.

引用

页码：1371 / 1378

页数：8

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