Synthesis and recognition studies with a ditopic, photoswitchable deep cavitand

被引:30
作者
Busseron, Eric
Lux, Jacques
Degardin, Melissa
Rebek, Julius, Jr. [1 ]
机构
[1] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA
关键词
FUNCTIONAL CAVITANDS; MOLECULAR MOTORS; CATALYSIS; COMPLEXES; MACHINES; RECEPTOR; LIGHT;
D O I
10.1039/c3cc41369a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We describe the synthesis and photochemical behavior of open-ended container modules connected by a 4,4'-azobiphenyl spacer. Both trans and cis azo configurations of the host can be accessed and their binding of guest molecules was characterized by NMR methods.
引用
收藏
页码:4842 / 4844
页数:3
相关论文
共 31 条
[1]  
Arduini A, 2000, EUR J ORG CHEM, V2000, P2325
[2]  
Balzani V, 2000, ANGEW CHEM INT EDIT, V39, P3348, DOI 10.1002/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO
[3]  
2-X
[4]   Light powered molecular machines [J].
Balzani, Vincenzo ;
Credi, Alberto ;
Venturi, Margherita .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (06) :1542-1550
[5]   Photochromic Blockers of Voltage-Gated Potassium Channels [J].
Banghart, Matthew R. ;
Mourot, Alexandre ;
Fortin, Doris L. ;
Yao, Jennifer Z. ;
Kramer, Richard H. ;
Trauner, Dirk .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (48) :9097-9101
[6]   Switchable Catalysis with a Light-Responsive Cavitand [J].
Berryman, Orion B. ;
Sather, Aaron C. ;
Lledo, Agusti ;
Rebek, Julius, Jr. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (40) :9400-9403
[7]   Improved functionality and control in the isomerization of a calix[4]arene-capped azobenzene [J].
Bonvallet, Paul A. ;
Mullen, Max R. ;
Evans, Paul J. ;
Stoltz, Kristen L. ;
Story, Erica N. .
TETRAHEDRON LETTERS, 2011, 52 (10) :1117-1120
[8]   Transition metal complexes as molecular machine prototypes [J].
Champin, Benoit ;
Mobian, Pierre ;
Sauvage, Jean-Pierre .
CHEMICAL SOCIETY REVIEWS, 2007, 36 (02) :358-366
[9]   A Rapidly Shuttling Copper-Complexed [2]Rotaxane with Three Different Chelating Groups in Its Axis [J].
Collin, Jean-Paul ;
Durola, Fabien ;
Lux, Jacques ;
Sauvage, Jean-Pierre .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (45) :8532-8535
[10]   Azobenzene-bridged calix[8]arenes [J].
Consoli, Grazia M. L. ;
Geraci, Corrada ;
Neri, Placido ;
Bergamini, Giacomo ;
Balzani, Vincenzo .
TETRAHEDRON LETTERS, 2006, 47 (44) :7809-7813