Synthesis of Ru-arene complexes of Me-Duphos. X-ray, PGSE NMR diffusion and catalytic studies

被引：39

作者：

Chen, Y

Valentini, M

Pregosin, PS ^{[1
]}

Albinati, A

机构：

[1] ETH Zurich, Anorgan Chem Lab, CH-8093 Zurich, Switzerland

[2] Univ Milan, I-20131 Milan, Italy

来源：

INORGANICA CHIMICA ACTA | 2002年 / 327卷

关键词：

Ru-arene complexes; Me-Duphos; PGSE; diffusion and catalytic studies;

D O I：

10.1016/S0020-1693(01)00680-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cationic [RuCl(arene)(Me-Duphos)]Cl complexes, arene = eta(6)-benzene and eta(6)-p-cymene, Me-Duphos = 1,2-bis-((2R,5R)-2,5-dimethylphospholano) benzene) have been prepared and studied by X-ray crystallography and NMR spectroscopy. PGSE NMR diffusion studies have been used to recognize (a) ion pairing as a function of solvent and (b) larger molecular volumes. Several arene-Ru-complexes have been shown to be useful catalyst precursors in the hydrolysis of terminal aryl alkynes to afford acetophenones. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：4 / 14

页数：11

共 62 条

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