(6Z,8Z)-2,4,6-trimethyl-8-phenyl-7-oxa-2,4-diazabicyclo[4.2.0]octane-3,5-dione

被引:3
作者
Prakash, G
Fettinger, JC
Falvey, DE
机构
[1] Dept. of Chemistry and Biochemistry, University of Maryland, College Park
关键词
D O I
10.1107/S0108270197002850
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, C14H16N2O3, is a model of the crucial intermediate in a postulated mechanism for the enzyme (6-4) photoproduct photolyase, which repairs a particular form of UV-light induced DNA damage. The dihedral angle of the two oxetane ring H atoms is 143.5 degrees, which means the bulky phenyl ring is exo to the pyrimidine ring.
引用
收藏
页码:979 / 981
页数:3
相关论文
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