Towards highly active and stable nickel-based metal-organic frameworks as ethylene oligomerization catalysts

被引：47

作者：

Arrozi, Ubed S. F. ^{[1
]}

Bon, Volodymyr ^{[1
]}

Kutzscher, Christel ^{[1
]}

Senkovska, Irena ^{[1
]}

Kaskel, Stefan ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Inorgan Chem, Bergstr 66, D-01062 Dresden, Germany

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 10期

关键词：

BUILDING UNITS; POLYMERIZATION; DIMERIZATION; TEMPERATURE; ADSORPTION; COMPLEXES; SITES;

D O I：

10.1039/c8dt03866j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Catalytic ethylene oligomerization proceeds under mild conditions with high activity using porous or non-porous nickel-based coordination polymers/metal-organic frameworks (MOFs) as catalysts. The role of MOFs as catalyst precursors and the crucial impact of metal coordination on the catalyst activity and leaching are elucidated by comparing MOFs constructed from different clusters and linkers. The stronger the coordination bond of organic linkers to the Ni center, the lower the catalytic activity of the MOF, as shown for CPO-27(Ni). The highest activity and stability were obtained with the [Ni-3(ndc)(3) (DMF)(2)((CH3)(2)NH)(2)](n) catalyst.

引用

页码：3415 / 3421

页数：7

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