High Resolution Study of the ν2 + ν10 Band of the 13C2H4 Molecule

被引：2

作者：

Onopenko, G. A. ^{[1
]}

Morzhikova, Yu. B. ^{[2
]}

Ziatkova, A. G. ^{[2
]}

Zamotaeva, V. A. ^{[2
]}

Buttersak, T. ^{[3
]}

机构：

[1] Tomsk State Univ Architecture & Bldg, Tomsk, Russia

[2] Tomsk Polytech Univ, Inst Phys & Technol Natl Res, Tomsk, Russia

[3] Tech Univ Carolo Wilhelmina Braunschweig, Braunschweig, Germany

来源：

RUSSIAN PHYSICS JOURNAL | 2017年 / 59卷 / 09期

关键词：

(C2H4)-C-13 molecule; rovibrational spectrum; parameters of the molecule Hamiltonian; RO-VIBRATIONAL ANALYSIS; MOLECULAR BANDS FORBIDDEN; LOCAL-MODE; ISOTOPE SUBSTITUTION; POLYATOMIC-MOLECULES; FTIR SPECTRUM; GROUND-STATE; HOT BANDS; ETHYLENE-C-13(2); REANALYSIS;

D O I：

10.1007/s11182-017-0914-0

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

High resolution (0.0025 cm(-1)) spectrum of the (C2H4)-C-13 molecule recorded in the 2330-2500 cm(-1) spectral region with a Bruker 120HR Fourier spectrometer is theoretically analyzed. The spectroscopic parameters of the (v(2) = v(10) = 1, B-2u) vibrational state of the molecule are determined for the first time by fitting the experimental data that allow the rotational energy values (529 rovibrational energies corresponding to 2400 transitions with J(max) = 30 and K-a (max) = 13) to be reproduced with accuracy close to experimental uncertainties.

引用

页码：1337 / 1342

页数：6

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