NHC-Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene

被引：78

作者：

Jana, Anukul ^{[1
]}

Huch, Volker ^{[1
]}

Scheschkewitz, David ^{[1
]}

机构：

[1] Univ Saarland, Krupp Chair Gen & Inorgan Chem, D-66125 Saarbrucken, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 46期

基金：

英国工程与自然科学研究理事会;

关键词：

carbene ligands; cycloaddition; germanium; silicon; vinylidenes; UNSATURATED CARBENES; KINETIC STABILITIES; TERMINAL ALKYNES; STABLE COMPOUND; CHEMICAL-SHIFTS; TRIPLE BONDS; ACETYLENE; DISILENES; GERMANIUM; SILICON;

D O I：

10.1002/anie.201306780

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stable vinylidene analogue: The synthesis of the first representative of a new compound class of low-valent Group14 elements, namely silagermenylidene A, is achieved by reduction of Tip2SiCl2 and NHC×GeCl2 (Tip=2,4,6-iPr3C6H2; NHC=1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene). The potential of A as a synthon is demonstrated by the formal [2+2] cycloaddition with phenylacetylene to afford NHC-stabilized cyclic germylene B. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12179 / 12182

页数：4

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