Simple, fast, and low-cost synthesis of MIL-100 and MIL-88B in a modified domestic microwave oven

被引：17

作者：

Aguiar, Lais W. ^{[1
]}

Otto, Guilherme P. ^{[1
]}

Kupfer, Vicente L. ^{[1
]}

Favaro, Silvia L. ^{[1
]}

Silva, Cleiser Thiago P. ^{[1
]}

Moises, Murilo P. ^{[2
]}

de Almeida, Leandro ^{[3
]}

Guilherme, Marcos R. ^{[3
]}

Radovanovic, Eduardo ^{[1
]}

Girotto, Emerson M. ^{[1
]}

Rinaldi, Andrelson W. ^{[1
]}

机构：

[1] State Univ Maringa UEM, Ave Colombo 5790,Zona 07, BR-87020900 Maringa, Parana, Brazil

[2] Fed Technol Univ Parana, BR-86812460 Apucarana, PR, Brazil

[3] Cesumar Inst Sci Technol & Innovat ICETI, Ave Guerdner 1610, BR-87050390 Maringa, Parana, Brazil

来源：

MATERIALS LETTERS | 2020年 / 276卷

关键词：

Biomaterials; Crystallization; MOF; Porous materials; Thermal mapping; METAL-ORGANIC FRAMEWORKS; ASSISTED SYNTHESIS; HYDROGEN STORAGE; FACILE SYNTHESIS; SELECTIVITY; COMPOSITE;

D O I：

10.1016/j.matlet.2020.128127

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

This work shows a facile modification of a modified domestic microwave oven that allows for the control of solvent losses and the monitoring of temperature during the synthesis of metal-organic frameworks (MOFs) MIL 100 under hydrofluoric acid-free conditions, HKUST-1 with unique properties, and MIL 88B. In order to obtain the best efficiency irradiation, a thermal mapping image from the domestic microwave DMW was obtained. The results showed that the chemical properties of the produced MOFs were excellent: the observed yield calculation and the BET surface area of the MIL-100 active crystals were 97% and 1300 m(2)g(-1), respectively, and 90% and 1365m(2)g(-1), respectively for HKUST-1 with unique properties. A simple and low-cost alternative to a commercial microwave oven was developed, making it safer and its parameters controllable during the synthesis of MOFs. (C) 2020 Elsevier B.V. All rights reserved.

引用

页数：4

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