The generation and trapping of enantiopure bromonium ions

被引：31

作者：

Braddock, D. Christopher ^{[1
]}

Hermitage, Stephen A. ^{[2
]}

Kwok, Lilian ^{[1
]}

Pouwer, Rebecca ^{[1
]}

Redmond, Joanna M. ^{[1
]}

White, Andrew J. P. ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] GlaxoSmithKline Ltd, Med Res Ctr, Stevenage SG1 2NY, Herts, England

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

STABLE CARBONIUM-IONS; C-13 ISOTOPE SHIFTS; ELECTROPHILIC BROMINATION; REVERSIBLE FORMATION; KINETIC APPROACH; EPOXIDES; ADAMANTYLIDENEADAMANTANE; CONVERSION; RESOLUTION; COMPLEXES;

D O I：

10.1039/b816914d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enantiopure bromonium ions may be generated from enantiopure bromohydrins and derivatives, they can be trapped with an in situ nucleophile to give enantiomerically pure products.

引用

页码：1082 / 1084

页数：3

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