Is xenon an "ennobled" alkane?

被引:26
作者
Filipe, EJM
Dias, LMB
Calado, JCG [1 ]
McCabe, C
Jackson, G
机构
[1] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal
[2] Colorado Sch Mines, Dept Chem Engn, Golden, CO 80401 USA
[3] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn & Chem Technol, London SW7 2BY, England
关键词
D O I
10.1039/b109165b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent studies on liquid mixtures involving xenon and the light n-alkanes have revealed that, in many ways, xenon behaves like a member of the n-alkane family. The observed behaviour can be interpreted at the molecular level in terms of size and intermolecular potential. In this work the extension of this analogy to other microscopic and macroscopic properties is discussed. Furthermore, this behaviour is confirmed by the anaesthetic power of xenon relatively to those of the n-alkanes. We believe that this result might contribute to a better understanding of the mechanism of anaesthesia at the molecular level.
引用
收藏
页码:1618 / 1621
页数:4
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