The effect of [(η3-C3H5)(η5-C5H5)Mo(CO)2] on drying of solvent-borne alkyd paints

被引：6

作者：

Preininger, Ondrej ^{[1
]}

Honzicek, Jan ^{[1
]}

Vinklarek, Jarornir ^{[2
]}

Erben, Milan ^{[2
]}

机构：

[1] Univ Pardubice, Fac Chem Technol, Inst Chem & Technol Macromol Mat, Pardubice 53210, Czech Republic

[2] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic

来源：

PROGRESS IN ORGANIC COATINGS | 2014年 / 77卷 / 02期

关键词：

Alkyd; Drier; Molybdenum; FTIR; Synergic effect; Autoxidation; COBALT; COMPLEXES; GENOTOXICITY; MOLYBDENUM; CATALYST; DRIERS;

D O I：

10.1016/j.porgcoat.2013.10.001

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Allyl molybdenum complex [(eta(3)-C3H5)(eta(5)-C5H5)Mo(CO)(2)] (Mo-A) was examined as a new drier for solvent-borne alkyd binder. The drying activity of pure Mo-A and the of combinations of Mo-A with cobalt(II) 2-ethylhexanoate (Co-Nuodex) was examined using standard methods for measurements of the drying time and hardness development of the alkyd film. The detailed study of the drying process was studied by time-resolved infrared spectroscopy on ethyl linoleate as well as on thin coating of alkyd binder. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：292 / 297

页数：6

共 27 条

[1] A simple entry to (η5-C5R5)chlorodioxomolybdenum(VI) complexes (R = H, CH3, CH2Ph) and their use as olefin epoxidation catalysts [J].

Abrantes, M ;

Santos, AM ;

Mink, J ;

Kühn, FE ;

Romao, CC .

ORGANOMETALLICS, 2003, 22 (10) :2112-2118

[2]

Bieleman JH, 2002, MACROMOL SYMP, V187, P811, DOI 10.1002/1521-3900(200209)187:1<811::AID-MASY811>3.0.CO

[3]

2-L

[4] Cobalt and antimony: genotoxicity and carcinogenicity [J].

De Boeck, Marlies ;

Kirsch-Volders, Micheline ;

Lison, Dominique .

MUTATION RESEARCH-FUNDAMENTAL AND MOLECULAR MECHANISMS OF MUTAGENESIS, 2003, 533 (1-2) :135-152

[5] The Quest for Cobalt-Free Alkyd Paint Driers [J].

de Boer, Johannes W. ;

Wesenhagen, Philana V. ;

Wenker, Erica C. M. ;

Maaijen, Karin ;

Gol, Franjo ;

Gibbs, Hugh ;

Hage, Ronald .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 2013 (21) :3581-3591

[6] Acyl-substituted ferrocenes as driers for solvent-borne alkyd paints [J].

Erben, Milan ;

Vesely, David ;

Vinklarek, Jaromir ;

Honzicek, Jan .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2012, 353 :13-21

[7] ORGANOMETALLIC CONFORMATIONAL EQUILIBRIA .16. STERIC EFFECTS ON PI-ALLYL AND PI-INDENYL ORIENTATION IN MOLYBDENUM AND TUNGSTEN COMPLEXES [J].

FALLER, JW ;

CHEN, CC ;

MATTINA, MJ ;

JAKUBOWS.A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 52 (02) :361-386

[8]

Freund C, 2007, TOP ORGANOMETAL CHEM, V22, P39, DOI 10.1007/3418_029

[9] Trace element risk assessment: essentiality vs. toxicity [J].

Goldhaber, SB .

REGULATORY TOXICOLOGY AND PHARMACOLOGY, 2003, 38 (02) :232-242

[10] The chronic toxicity of molybdate to marine organisms. I. Generating reliable effects data [J].

Heijerick, D. G. ;

Regoli, L. ;

Stubblefield, W. .

SCIENCE OF THE TOTAL ENVIRONMENT, 2012, 430 :260-269

← 1 2 3 →