Ionic liquid-based synthesis of MXene

被引:96
作者
Husmann, Samantha [1 ]
Budak, Oznil [1 ,2 ]
Shim, Hwirim [1 ,2 ]
Liang, Kun [3 ]
Aslan, Mesut [1 ]
Kruth, Angela [4 ]
Quade, Antje [4 ]
Naguib, Michael [3 ]
Presser, Volker [1 ,2 ]
机构
[1] INM Leibniz Inst New Mat, Campus D2 2, D-66123 Saarbrucken, Germany
[2] Saarland Univ, Dept Mat Sci & Engn, Campus D2 2, D-66123 Saarbrucken, Germany
[3] Tulane Univ, Dept Phys & Engn Phys, New Orleans, LA 70118 USA
[4] Leibniz Inst Plasma Sci & Technol, D-17489 Greifswald, Germany
关键词
TI3ALC2; PHASES;
D O I
10.1039/d0cc03189e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
MAX phases are etched using an ionic liquid-water mixture to produce titanium carbide MXenes. The process avoids the use of any acid. Hydrolysis of the fluorine-containing ionic liquid leads to the selective removal of Al, while the ionic liquid is intercalated in-between the transition metal carbide layers.
引用
收藏
页码:11082 / 11085
页数:4
相关论文
共 20 条
[1]   2D metal carbides and nitrides (MXenes) for energy storage [J].
Anasori, Babak ;
Lukatskaya, Maria R. ;
Gogotsi, Yury .
NATURE REVIEWS MATERIALS, 2017, 2 (02)
[2]   The MN+1AXN phases:: A new class of solids;: Thermodynamically stable nanolaminates [J].
Barsoum, MW .
PROGRESS IN SOLID STATE CHEMISTRY, 2000, 28 (1-4) :201-281
[3]  
Borun A, 2015, INT J ELECTROCHEM SC, V10, P2120
[4]  
Bragg WH, 1913, P R SOC LOND A-CONTA, V88, P428, DOI 10.1098/rspa.1913.0040
[5]   Nanostructure of the Ionic Liquid-Graphite Stern Layer [J].
Elbourne, Aaron ;
McDonald, Semila ;
Voichovsky, Kislon ;
Endres, Frank ;
Warr, Gregory G. ;
Atkin, Rob .
ACS NANO, 2015, 9 (07) :7608-7620
[6]   Hydrolysis of Tetrafluoroborate and Hexafluorophosphate Counter Ions in Imidazolium-Based Ionic Liquids [J].
Freire, Mara G. ;
Neves, Catarina M. S. S. ;
Marrucho, Isabel M. ;
Coutinho, Joao A. P. ;
Fernandes, Ana M. .
JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 114 (11) :3744-3749
[7]   Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance [J].
Ghidiu, Michael ;
Lukatskaya, Maria R. ;
Zhao, Meng-Qiang ;
Gogotsi, Yury ;
Barsoum, Michel W. .
NATURE, 2014, 516 (7529) :78-U171
[8]   Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films [J].
Halim, Joseph ;
Lukatskaya, Maria R. ;
Cook, Kevin M. ;
Lu, Jun ;
Smith, Cole R. ;
Naslund, Lars-Ake ;
May, Steven J. ;
Hultman, Lars ;
Gogotsi, Yury ;
Eklund, Per ;
Barsoum, Michel W. .
CHEMISTRY OF MATERIALS, 2014, 26 (07) :2374-2381
[9]   Vibrational properties of Ti3C2 and Ti3C2T2 (T = O, F, OH) monosheets by first-principles calculations: a comparative study [J].
Hu, Tao ;
Wang, Jiemin ;
Zhang, Hui ;
Li, Zhaojin ;
Hu, Minmin ;
Wang, Xiaohui .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (15) :9997-10003
[10]   In Situ Electrical Conductivity of LixMnO2 Nanowires as a Function of x and Size [J].
Le, Mya ;
Liu, Yu ;
Wang, Hui ;
Dutta, Rajen K. ;
Yan, Wenbo ;
Hemminger, John C. ;
Wu, Ruqian Q. ;
Penner, Reginald M. .
CHEMISTRY OF MATERIALS, 2015, 27 (09) :3494-3504