Chelating palladium complexes containing pyridine/pyrimidine hydroxyalkyl di-functionalized N-heterocyclic carbenes: synthesis, structure, and catalytic activity towards C-H activation

被引：19

作者：

Yang, Liangru ^{[1
]}

Yuan, Jinwei ^{[1
]}

Mao, Pu ^{[1
]}

Guo, Qi ^{[1
]}

机构：

[1] Henan Univ Technol, Sch Chem & Chem Engn, Zhengzhou 450001, Peoples R China

来源：

RSC ADVANCES | 2015年 / 5卷 / 130期

基金：

中国国家自然科学基金;

关键词：

HIGHLY EFFICIENT; CHLORIDE COMPLEXES; PLATINUM COMPLEXES; DIRECT ARYLATION; LIGANDS; RHODIUM; HYDROGENATION; BENZOXAZOLES; PRECURSORS; CHEMISTRY;

D O I：

10.1039/c5ra21183b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of novel chelating palladium complexes containing pyridine/pyrimidine hydroxyalkyl di-functionalized N-heterocyclic carbenes (NHCs) via direct metallation of the precursor imidazolium salts is presented. The structure has been characterized unambiguously by X-ray single crystal analysis. Catalytic activity investigation showed that the complexes catalyse the direct C-H bond arylation of (benzo)oxazoles efficiently when using (BuOLi)-Bu-t as base and DMF as solvent.

引用

页码：107601 / 107607

页数：7

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