Copper-catalyzed ortho-halogenation of protected anilines

被引：88

作者：

Urones, Beatriz ^{[1
]}

Manu Martinez, Angel ^{[1
]}

Rodriguez, Nuria ^{[1
]}

Gomez Arrayas, Ramon ^{[1
]}

Carretero, Juan C. ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 94期

关键词：

H BOND ACTIVATION; MOLECULAR-OXYGEN; PALLADIUM; FUNCTIONALIZATION; OXIDATION;

D O I：

10.1039/c3cc47174h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A practical Cu-catalyzed direct ortho-halogenation of anilines under aerobic conditions has been developed. The reaction shows typically excellent mono-substitution selectivity, high ortho-regiocontrol and large functional group tolerance.

引用

页码：11044 / 11046

页数：3

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