Study the effect of acetic acid on structural, optical and mechanical properties of PVA/chitosan/MWCNT films

被引:57
作者
Abdolrahimi, Maryam [1 ]
Seifi, Majid [1 ]
Ramezanzadeh, Mohammad Hassan [1 ]
机构
[1] Univ Guilan, Dept Phys, Fac Sci, Rasht 41335, Iran
关键词
Nanocomposite films; Carbon nanotubes; Solution-casting; Optical properties; Mechanical properties; MULTIWALLED CARBON NANOTUBES; COMPOSITE; CONDUCTIVITY; ABSORPTION;
D O I
10.1016/j.cjph.2017.12.018
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Polyvinyl alcohol (PVA)/chitosan/multiwalled carbon nanotube (MWCNT) films were successfully prepared by using solution-casting method. Structural properties were studied using Fourier transform infrared (FTIR) and X-ray diffraction (XRD) spectroscopies. The effect of acetic acid (AA) concentration on the films optical parameters was studied by using absorbance and transmittance data recorded during ultraviolet-visible (UV-Vis) spectroscopy. The results indicated that increasing the AA concentration in MWCNT-reinforced PVA films caused an increase in their optical capability. We also evaluated mechanical properties such as stress-strain behavior, Young's modulus, tensile strength, elongation at break, etc. Mechanical indices have been modified by introducing carbon nanotubes, even though enhancing the AA concentration meets significant restrictions on higher percentages of AA concentration, which needs to be delicately considered. The porous structure of the films, such as porous pattern, materials' diameter, and shape was examined by field emission electron microscopy (FESEM). Engineering analyses showed that the films reinforced with MWCNTs exhibited an interconnected homogenous structure in various acid concentrations.
引用
收藏
页码:221 / 230
页数:10
相关论文
共 27 条
[1]   Cerium (III) doping effects on optical and thermal properties of PVA films [J].
Abdelaziz, M. .
PHYSICA B-CONDENSED MATTER, 2011, 406 (6-7) :1300-1307
[2]   Carbon nanotube electronics [J].
Avouris, P .
CHEMICAL PHYSICS, 2002, 281 (2-3) :429-445
[3]  
Buang NA, 2012, DIG J NANOMATER BIOS, V7, P33
[4]   Enhanced mechanical properties and morphological characterizations of poly(vinyl alcohol)-carbon nanotube composite films [J].
Chen, W ;
Tao, XM ;
Xue, P ;
Cheng, XY .
APPLIED SURFACE SCIENCE, 2005, 252 (05) :1404-1409
[5]   CONDUCTION IN NON-CRYSTALLINE SYSTEMS .5. CONDUCTIVITY, OPTICAL ABSORPTION AND PHOTOCONDUCTIVITY IN AMORPHOUS SEMICONDUCTORS [J].
DAVIS, EA ;
MOTT, NF .
PHILOSOPHICAL MAGAZINE, 1970, 22 (179) :903-&
[6]   Review of the doping of carbon nanotubes (multiwalled and single-walled) [J].
Duclaux, L .
CARBON, 2002, 40 (10) :1751-1764
[7]   Role of Carbon Source in the Synthesis of Carbon Nanotubes via Catalytic Chemical Vapour Deposition [J].
Fatiha, Ismail ;
Nor, Aziah Buang ;
Othman, Muhammad Zamir .
NANOMATERIALS: SYNTHESIS AND CHARACTERIZATION, 2012, 364 :16-19
[8]   Simultaneous Reduction and Surface Functionalization of Graphene Oxide by Chitosan and Their Synergistic Reinforcing Effects in PVA Films [J].
Feng, Xiaming ;
Wang, Xin ;
Xing, Weiyi ;
Yu, Bin ;
Song, Lei ;
Hu, Yuan .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (36) :12906-12914
[9]  
Hassan CM, 1998, WATER SOLUBLE POLYMERS: SOLUTION PROPERTIES AND APPLICATIONS, P31
[10]   Water absorption and states of water in semicrystalline poly(vinyl alcohol) films [J].
Hodge, RM ;
Edward, GH ;
Simon, GP .
POLYMER, 1996, 37 (08) :1371-1376