Metal catalyzed C(sp3)-H bond amination of 2-alkyl azaarenes with diethyl azodicarboxylate

被引：69

作者：

Liu, Jin-Ying ^{[1
]}

Niu, Hong-Ying ^{[2
]}

Wu, Shan ^{[1
]}

Qu, Gui-Rong ^{[1
]}

Guo, Hai-Ming ^{[1
]}

机构：

[1] Henan Normal Univ, Minist Educ, Key Lab Green Chem Media & React, Coll Chem & Environm Sci, Xinxiang 453007, Henan, Peoples R China

[2] Henan Inst Sci & Technol, Sch Chem & Chem Engn, Xinxiang 453003, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 78期

基金：

中国国家自然科学基金;

关键词：

ENANTIOSELECTIVE ALPHA-AMINATION; SITE-SELECTIVE SP(2); C-H AMINATION; AMIDATION; ALDEHYDES;

D O I：

10.1039/c2cc35309a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-catalyzed direct C(sp(3))-H bond amination of 2-alkyl azaarenes with N=N double bonds has been developed, which expands the scope of C(sp(3))-H bond activation reactions and provides a new access to medicinally important azaarene derivatives.

引用

页码：9723 / 9725

页数：3

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