Iron triflate catalyzed reductive amination of aldehydes using sodium borohydride

被引：44
作者：
Kumar, N. Uday [1 ]
Reddy, B. Sudhakar [1 ]
Reddy, V. Prabhakar [2 ]
Bandichhor, Rakeshwar [1 ]
机构：
[1] Dr Reddys Labs Ltd, Integrated Prod Dev, Qutubullapur 500072, Andhra Pradesh, India
[2] Osmania Univ, Dept Chem, Hyderabad 500007, Andhra Pradesh, India
来源：
TETRAHEDRON LETTERS | 2012年 / 53卷 / 33期
关键词：
Reductive amination; Iron triflate; Sodium borohydride; CARBONYL-COMPOUNDS; TITANIUM(IV) ISOPROPOXIDE; ZINC BOROHYDRIDE; KETONES; IMINES; AMINES; EFFICIENT; SOLVENT; MILD; ALKYLATION;
D O I：
10.1016/j.tetlet.2012.06.018
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient and convenient procedure for the reductive amination of aldehydes using NaBH4 in the presence of catalytic amount of Fe(OTf)(3) is described. (C) 2012 Elsevier Ltd. All rights reserved.
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收藏
页码：4354 / 4356
页数：3
相关论文
共 57 条
[1]   Reductive amination of aldehydes and ketones with sodium triacetoxyborohydride. Studies on direct and indirect reductive amination procedures [J].
AbdelMagid, AF ;
Carson, KG ;
Harris, BD ;
Maryanoff, CA ;
Shah, RD .
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (11) :3849-3862
[2]  
Akbar H., 2007, J MOL CATAL A-CHEM, V274, P169
[3]  
[Anonymous], CPMPSWPQWP444600
[4]   Direct reductive amination of aldehydes and ketones using phenylsilane: Catalysis by dibutyltin dichloride [J].
Apodaca, R ;
Xiao, W .
ORGANIC LETTERS, 2001, 3 (11) :1745-1748
[5]  
Bae JW, 2000, J CHEM SOC PERK T 1, P145
[6]   Direct reductive amination of carbonyl compounds using bis(triphenylphosphine) copper(I) tetrahydroborate [J].
Bhanushali, Mayur J. ;
Nandurkar, Nitin S. ;
Bhor, Malhari D. ;
Bhanage, Bhalchandra M. .
TETRAHEDRON LETTERS, 2007, 48 (07) :1273-1276
[7]   REDUCTIVE ALKYLATIONS OF DIMETHYLAMINE USING TITANIUM(IV) ISOPROPOXIDE AND SODIUM-BOROHYDRIDE - AN EFFICIENT, SAFE, AND CONVENIENT METHOD FOR THE SYNTHESIS OF N,N-DIMETHYLATED TERTIARY-AMINES [J].
BHATTACHARYYA, S .
JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (15) :4928-4929
[8]   Reductive amination with zinc borohydride. Efficient, safe route to fluorinated benzylamines [J].
Bhattacharyya, S ;
Chatterjee, A ;
Williamson, JS .
SYNTHETIC COMMUNICATIONS, 1997, 27 (24) :4265-4274
[9]   Direct reductive amination of carbonyl compounds with primary/secondary amines using recyclable water-soluble FeII/EDTA complex as catalyst [J].
Bhor, Malhari D. ;
Bhanushali, Mayur J. ;
Nandurkar, Nam S. ;
Bhanage, Bhalchandra M. .
TETRAHEDRON LETTERS, 2008, 49 (06) :965-969
[10]   B(C6F5)3-catalyzed hydrosilation of imines via silyliminium intermediates [J].
Blackwell, JM ;
Sonmor, ER ;
Scoccitti, T ;
Piers, WE .
ORGANIC LETTERS, 2000, 2 (24) :3921-3923
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