Enhancing the low temperature water-gas shift reaction through a hybrid sorption-enhanced membrane reactor for high-purity hydrogen production

被引：43

作者：

Soria, M. A. ^{[1
]}

Tosti, S. ^{[2
]}

Mendes, A. ^{[1
]}

Madeira, Luis M. ^{[1
]}

机构：

[1] Univ Porto, Fac Engn, LEPABE Chem Engn Dept, P-4200465 Oporto, Portugal

[2] CR ENEA Frascati, ENEA Unita Tecn Fus, I-00044 Frascati, RM, Italy

来源：

FUEL | 2015年 / 159卷

关键词：

Water-gas shift; Hydrotalcite; CO2; sorption; Membrane reactor; Sorption enhanced; Hydrogen; HYDROTALCITE-LIKE COMPOUNDS; CO2; SORPTION; CARBON-DIOXIDE; CAPTURE; DECOMPOSITION; REMOVAL; H-2; CHEMISORPTION; ADSORPTION; SORBENTS;

D O I：

10.1016/j.fuel.2015.07.035

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The low temperature water-gas-shift reaction (LT-WGS) has been assessed by means of a hybrid sorption-enhanced membrane reactor (HSEMR) that combines both CO2 and H-2 removal from the reaction zone. The performance of this reactor has been compared with that obtained by (i) a traditional and (ii) a sorption-enhanced (only CO2 is removed) reactor operating in the same operational conditions. Cu/ZnO-Al2O3 and K2CO3-promoted hydrotalcite materials have been used as a catalyst and CO2 sorbent, respectively. A self-supported Pd-Ag membrane tube has been used in order to selectively separate the H-2. The CO2 sorption capacity, in the presence and absence of water vapour, of the potassium-promoted hydrotalcite has been determined by means of breakthrough experiments. The presence of water vapour enhanced the sorption capacity of the hydrotalcite in the experimental conditions used. Concerning the performance of the HSERM, results clearly show that when both CO2 and H-2 are removed from the reaction zone, the hydrogen production through the reversible LT-WGS reaction is enhanced compared to either a traditional or a sorption-enhanced reactor, allowing overcoming equilibrium limitations and obtain a pure H-2 stream. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：854 / 863

页数：10

共 36 条

[11] Chemisorption of carbon dioxide on potassium-carbonate-promoted hydrotalcite [J].

Lee, K. B. ;

Verdooren, A. ;

Caram, H. S. ;

Sircar, S. .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 308 (01) :30-39

[12] The removal of naphthenic acids from dewaxed VGO via esterification catalyzed by Mg-Al hydrotalcite [J].

Li, Xiaohui ;

Zhu, Jianhua ;

Liu, Qingliu ;

Wu, Bencheng .

FUEL PROCESSING TECHNOLOGY, 2013, 111 :68-77

[13] Performance of a Pd/PSS membrane reactor to produce high purity hydrogen via WGS reaction [J].

Liguori, S. ;

Pinacci, P. ;

Seelam, P. K. ;

Keiski, R. ;

Drago, F. ;

Calabro, V. ;

Basile, A. ;

Iulianelli, A. .

CATALYSIS TODAY, 2012, 193 (01) :87-94

[14] Facile synthesis of hydrotalcite and its thermal decomposition kinetics mechanism study with masterplots method [J].

Long, Qiwei ;

Xia, Yao ;

Liao, Sen ;

Li, Yu ;

Wu, Wenwei ;

Huang, Yingheng .

THERMOCHIMICA ACTA, 2014, 579 :50-55

[15] Experimental studies of CO2 capture by a hybrid catalyst/adsorbent system applicable to IGCC processes [J].

Marono, Marta ;

Torreiro, Yarima ;

Cillero, Domingo ;

Maria Sanchez, Jose .

APPLIED THERMAL ENGINEERING, 2015, 74 :28-35

[16] Development of new CaO based sorbent materials for CO2 removal at high temperature [J].

Martavaltzi, Christina S. ;

Lemonidou, Angeliki A. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 110 (01) :119-127

[17] Improved carbon dioxide capture using metal reinforced hydrotalcite under wet conditions [J].

Martunus ;

Helwani, Z. ;

Wiheeb, A. D. ;

Kim, J. ;

Othman, M. R. .

INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL, 2012, 7 :127-136

[18] Elevated temperature carbon dioxide capture via reinforced metal hydrotalcite [J].

Martunus ;

Othman, M. R. ;

Fernando, W. J. N. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2011, 138 (1-3) :110-117

[19] The water-gas shift reaction: from conventional catalytic systems to Pd-based membrane reactors - a review [J].

Mendes, D. ;

Mendes, A. ;

Madeira, L. M. ;

Iulianelli, A. ;

Sousa, J. M. ;

Basile, A. .

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, 2010, 5 (01) :111-137

[20] Experimental and modeling studies on the low-temperature water-gas shift reaction in a dense Pd-Ag packed-bed membrane reactor [J].

Mendes, Diogo ;

Sa, Sandra ;

Tosti, Silvano ;

Sousa, Jose M. ;

Madeira, Luis M. ;

Mendes, Adelio .

CHEMICAL ENGINEERING SCIENCE, 2011, 66 (11) :2356-2367

← 1 2 3 4 →