[HyEtPy]Cl-H2O: an efficient and versatile solvent system for the DABCO-catalyzed Morita-Baylis-Hillman reaction

被引:11
作者
Zhao, Sanhu [1 ,2 ]
He, Meiyan [1 ]
Guo, Zhaonan [1 ]
Zhou, Na [1 ]
Wang, Dou [1 ]
Li, Jinlong [1 ]
Zhang, Liwei [2 ]
机构
[1] Xinzhou Teachers Univ, Dept Chem, Xinzhou 034000, Shanxi, Peoples R China
[2] Shanxi Univ, Educ Minist, Key Lab Chem Biol & Mol Engn, Inst Mol Sci, Taiyuan 030006, Shanxi, Peoples R China
关键词
IONIC LIQUIDS; RATE ACCELERATION; QUINUCLIDINE; ENHANCEMENT; PRESSURE; WATER;
D O I
10.1039/c5ra02102b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient and versatile solvent-catalyst system, [HyEtPy]Cl-H2O-DABCO, has been developed and used in the Morita-Baylis-Hillman reaction. Under the mild reaction conditions, Morita-Baylis-Hillman proceeds very quickly and efficiently. This protocol has notable advantages such as eco-friendliness, ease of work-up and reuse of ionic liquid conveniently, which could help reduce disposal costs and contribute to the development of a new solvent-catalyst system for use in green and continuous chemical processes.
引用
收藏
页码:32839 / 32845
页数:7
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