Distribution of Tm3+ and Ni2+ in chalcogenide glass ceramics containing Ga2S3 nanocrystals: Influence on photoluminescence properties

被引：20

作者：

Lu, Xiaosong ^{[1
]}

Lai, Zhiqiang ^{[1
]}

Ren, Jing ^{[1
]}

Strizik, Lukas ^{[2
]}

Wagner, Tomas ^{[2
,3
]}

Du, Yanqiu ^{[1
]}

Farrell, Gerald ^{[4
]}

Wang, Pengfei ^{[1
,5
]}

机构：

[1] Harbin Engn Univ, Key Lab In Fiber Integrated Opt, Minist Educ China, Harbin 150001, Heilongjiang, Peoples R China

[2] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, Studentska 573, Pardubice 53210, Czech Republic

[3] Univ Pardubice, Ctr Mat & Nanotechnol, Studentska 573, Pardubice 53210, Czech Republic

[4] Dublin Inst Technol, Photon Res Ctr, Kevin St, Dublin 8, Ireland

[5] Shenzhen Univ, Coll Optoelect Engn, Minist Educ & Guangdong Prov, Key Lab Optoelect Devices & Syst, Shenzhen 518060, Peoples R China

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2019年 / 39卷 / 07期

基金：

黑龙江省自然科学基金; 中国国家自然科学基金;

关键词：

Chalcogenide glass; Glass ceramics; Ga2S3; Enhanced mid-infrared luminescence; RARE-EARTH IONS; MU-M EMISSION; MIDINFRARED EMISSION; FIBERS; DY3+;

D O I：

10.1016/j.jeurceramsoc.2019.01.055

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The distribution of Tm3+ and Ni2+ ions is unambiguously exhibited in 80GeS(2)-20Ga(2)S(3) chalcogenide glass ceramics (GCs) containing Ga2S3 nanocrystals (NCs) by using advanced analytical transmission electron microscopy. Distinctively different distribution patterns of Tm3+ and Ni2+ ions are observed in the GCs obtained by controlled crystallization. The distribution of the dopants imposes strong influence on their optical properties which are revealed by absorption and photoluminescence (PL) spectra. Detailed discussions are given of the mechanisms of the crystallization-induced PL enhancement and quenching of the Tm3+ mid-infrared and Ni2+ near-infrared emissions, respectively.

引用

页码：2580 / 2584

页数：5

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