Enhanced performance of perovskite solar cells by incorporation of a triphenylamine derivative into hole-transporting poly(3-hexylthiophene) layers

被引：14
作者：
Kim, Ji Young [1 ,2 ]
Kwak, Giseop [2 ]
Choi, Yong Chan [1 ]
Kim, Dae-Hwan [1 ]
Han, Yoon Soo [3 ]
机构：
[1] Daegu Gyeongbuk Inst Sci & Technol, Convergence Res Ctr Solar Energy, Daegu 42988, South Korea
[2] Kyungpook Natl Univ, Dept Polymer Sci & Engn, Daegu 41566, South Korea
[3] Daegu Catholic Univ, Sch Adv Mat & Chem Engn, Gyeongbuk 38430, South Korea
来源：
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2019年 / 73卷
基金：
新加坡国家研究基金会;
关键词：
Perovskite solar cell; Poly(3-hexylthiophene); m-MTDATA; Additive; Hole mobility; OPEN-CIRCUIT VOLTAGE; EFFICIENCY; TIO2; MOBILITY; POLYMER; PHASE; FILMS;
D O I：
10.1016/j.jiec.2019.01.022
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A 4,4',4 ''-tris[phenyl(m-tolyl)amino]triphenylamine (m-MIDATA) was applied as an additive to hole transporting poly(3-hexylthiophene) [P3HT] layers in perovskite solar cells. The incorporation of 0.5 wt% m-MTDATA to the P3HT layer led to an increased power conversion efficiency of 9.53%, due to an enhancement in the short circuit current, open-circuit voltage and fill factor, compared with that (8.76%) of the control cell without the additive. This enhanced performance was attributed to an increase in the hole mobility and a decrease in the charge recombination of the device with the P3HT:m-MTDATA blend film, compared to those of the control device with the pristine P3HT film. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：175 / 181
页数：7
相关论文
共 47 条
[1]   A combined single crystal neutron/X-ray diffraction and solid-state nuclear magnetic resonance study of the hybrid perovskites CH3NH3PbX3 (X = I, Br and Cl) [J].
Baikie, Tom ;
Barrow, Nathan S. ;
Fang, Yanan ;
Keenan, Philip J. ;
Slater, Peter R. ;
Piltz, Ross O. ;
Gutmann, Matthias ;
Mhaisalkar, Subodh G. ;
White, Tim J. .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (17) :9298-9307
[2]   Low-temperature processed meso-superstructured to thin-film perovskite solar cells [J].
Ball, James M. ;
Lee, Michael M. ;
Hey, Andrew ;
Snaith, Henry J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1739-1743
[3]   Practical Efficiency Limit of Methylammonium Lead Iodide Perovskite (CH3NH3PbI3) Solar Cells [J].
Baloch, Ahmer A. B. ;
Hossain, M. I. ;
Tabet, N. ;
Alharbi, F. H. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2018, 9 (02) :426-434
[4]   Analysis of Electron Transfer Properties of ZnO and TiO2 Photoanodes for Dye-Sensitized Solar Cells [J].
Chandiran, Aravind Kumar ;
Abdi-Jalebi, Mojtaba ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
ACS NANO, 2014, 8 (03) :2261-2268
[5]   Efficiency Enhancement of Hybrid Perovskite Solar Cells with MEH-PPV Hole-Transporting Layers [J].
Chen, Hsin-Wei ;
Huang, Tzu-Yen ;
Chang, Ting-Hsiang ;
Sanehira, Yoshitaka ;
Kung, Chung-Wei ;
Chu, Chih-Wei ;
Ikegami, Masashi ;
Miyasaka, Tsutomu ;
Ho, Kuo-Chuan .
SCIENTIFIC REPORTS, 2016, 6
[6]   Thermally stable propanethiol-ligand exchanged Ag nanoparticles for enhanced dispersion in perovskite solar cells via an effective incorporation method [J].
Cho, Jae Sang ;
Jang, Woongsik ;
Park, Soyun ;
Kim, Byung Ki ;
Wang, Dong Hwan .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2018, 61 :71-77
[7]   Antisolvent-assisted powder engineering for controlled growth of hybrid CH3NH3PbI3 perovskite thin films [J].
Choi, Yong Chan ;
Lee, Se Won ;
Kim, Dae-Hwan .
APL MATERIALS, 2017, 5 (02)
[8]   Controlled growth of organic-inorganic hybrid CH3NH3PbI3 perovskite thin films from phase-controlled crystalline powders [J].
Choi, Yong Chan ;
Lee, Se Won ;
Jo, Hyo Jeong ;
Kim, Dae-Hwan ;
Sung, Shi-Joon .
RSC ADVANCES, 2016, 6 (106) :104359-104365
[9]   An Inorganic Hole Conductor for Organo-Lead Halide Perovskite Solar Cells. Improved Hole Conductivity with Copper Iodide [J].
Christians, Jeffrey A. ;
Fung, Raymond C. M. ;
Kamat, Prashant V. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) :758-764
[10]   Enhanced hole mobility in regioregular polythiophene infiltrated in straight nanopores [J].
Coakley, KM ;
Srinivasan, BS ;
Ziebarth, JM ;
Goh, C ;
Liu, YX ;
McGehee, MD .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (12) :1927-1932
12345