Structure and magnetic properties of a new dinuclear nickel(II) complex with a dinucleating hexaazamacrocycle

被引：4
作者：
Zhu, HL
Wu, MF
Zheng, LM
Huang, P
Tang, WX [1 ]
Bu, WM
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Jilin Univ, Key Lab Supermol Struct & Spect, Changchun 130023, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 1999年 / 24卷 / 03期
关键词：
D O I：
10.1023/A:1006972423053
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure and magnetic properties of a new dinuclear nickel(II) complex [LNi2(AcO)(4)]. 14H(2)O, where L = 3,6,9,17,20,23-hexaazatricyclo [23.3.1.1(11,13)] triaconta-1(29),11(30),12,14,25(26),27-hexene, has been studied. X-ray structure analysis shows that the compound consists of a discrete [LNi2(AcO)(4)] complex and 14 lattice water molecules. Each Ni atom is six coordinated by three N atoms from the macrocycle and three O atoms from the two coordinated acetates; two nickel atoms in each macrocycle are at the distance of 7.028 Angstrom. The result of the magnetic measurement indicates that the zero-field splitting constant of nickel(II) centres \D\ = 1.87 cm(-1).
引用
收藏
页码：346 / 349
页数：4
相关论文
共 50 条
[41]   Synthesis, Structure and CD Spectra of Chiral Dinuclear Nickel(II) Complex [J].
Xiang Hua ;
Jiang Long ;
Li Huan-Yong ;
Zheng Xiao-Dan ;
Li Yu .
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2013, 29 (05) :1084-1088
[42]   A new dinuclear copper(II) complex of a bis-macrocyclic ligand: Synthesis, characterization, crystal structure and magnetic properties [J].
Du, M ;
Xu, Q ;
Guo, YM ;
Weng, LH ;
Bu, XH .
CHINESE JOURNAL OF CHEMISTRY, 2001, 19 (08) :778-782
[43]   DINUCLEAR NICKEL(II) COMPLEXES OF A SERIES OF DINUCLEATING MACROCYCLES WITH SIMILAR OR DISSIMILAR COORDINATION SITES - SYNTHESIS, STRUCTURE AND PHYSICOCHEMICAL PROPERTY [J].
ARATAKE, Y ;
OHBA, M ;
SAKIYAMA, H ;
TADOKORO, M ;
MATSUMOTO, N ;
OKAWA, H .
INORGANICA CHIMICA ACTA, 1993, 212 (1-2) :183-190
[44]   Synthesis, crystal structure and spectroscopic properties of a dinuclear nickel(II) complex bridged by an alkoxide and a μ-pyrazolate ligand [J].
Kara, H ;
Elerman, Y ;
Elmali, A .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2003, 58 (10) :955-958
[45]   Intriguing assembled structure and properties of a novel dinuclear nickel(II) complex with an axially coordinated azide and methanol [J].
Ishikawa, Ryuta ;
Fuyuhiro, Akira ;
Hayami, Shinya ;
Inoue, Katsuya ;
Kawata, Satoshi .
JOURNAL OF MOLECULAR STRUCTURE, 2008, 892 (1-3) :220-224
[46]   Electronic spectrum and magnetic properties of a dinuclear nickel(II) complex with two nickel(II) ions of C2-twisted octahedral geometry [J].
Sakiyama, Hiroshi ;
Tone, Katsuya ;
Yamasaki, Mikio ;
Mikuriya, Masahiro .
INORGANICA CHIMICA ACTA, 2011, 365 (01) :183-189
[47]   DNA-binding and cleavage studies of a dinuclear copper(II) complex with a 26-membered hexaazamacrocycle [J].
Jie Liu ;
Tong-Bu Lu ;
Hong Li ;
Qian-Ling Zhang ;
Liang-Nian Ji ;
Ti-Xiang Zhang ;
Liang-Hu Qu ;
Hui Zhou .
Transition Metal Chemistry, 2002, 27 :686-690
[48]   Synthesis, structure and properties of a new dinuclear Co(II) triple-helical complex [J].
Xu, L ;
Chen, XT ;
Xu, Y ;
Zhu, DR ;
You, XZ ;
Weng, LH .
JOURNAL OF MOLECULAR STRUCTURE, 2001, 559 (1-3) :361-368
[49]   Hydrothermal Synthesis, Crystal Structure, Thermal Stability and Magnetic Properties of a Dinuclear Copper(II) Complex [J].
Li Chang-Hong ;
Li Wei ;
Hu Han-Xiang ;
Hu Bo-Nian .
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (10) :1553-1557
[50]   SYNTHESIS, CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF DINUCLEAR NICKEL(II) COMPLEXES BRIDGED BY OXAMIDES [J].
CHEN, ZN ;
TANG, WX ;
CHEN, J ;
ZHENG, PJ ;
CHEN, CG ;
YU, KB .
POLYHEDRON, 1994, 13 (6-7) :873-879
12345