Structure and magnetic properties of a new dinuclear nickel(II) complex with a dinucleating hexaazamacrocycle

被引：4
作者：
Zhu, HL
Wu, MF
Zheng, LM
Huang, P
Tang, WX [1 ]
Bu, WM
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Jilin Univ, Key Lab Supermol Struct & Spect, Changchun 130023, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 1999年 / 24卷 / 03期
关键词：
D O I：
10.1023/A:1006972423053
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure and magnetic properties of a new dinuclear nickel(II) complex [LNi2(AcO)(4)]. 14H(2)O, where L = 3,6,9,17,20,23-hexaazatricyclo [23.3.1.1(11,13)] triaconta-1(29),11(30),12,14,25(26),27-hexene, has been studied. X-ray structure analysis shows that the compound consists of a discrete [LNi2(AcO)(4)] complex and 14 lattice water molecules. Each Ni atom is six coordinated by three N atoms from the macrocycle and three O atoms from the two coordinated acetates; two nickel atoms in each macrocycle are at the distance of 7.028 Angstrom. The result of the magnetic measurement indicates that the zero-field splitting constant of nickel(II) centres \D\ = 1.87 cm(-1).
引用
收藏
页码：346 / 349
页数：4
相关论文
共 50 条
[31]   A nickel(II) complex with imino nitroxide radicals: structure and magnetic properties [J].
Li, LC ;
Liao, DZ ;
Jiang, ZH ;
Yan, SP .
JOURNAL OF MOLECULAR STRUCTURE, 2003, 649 (1-2) :37-42
[32]   Structure and magnetic properties of a trinuclear nickel(II) complex with benzenetricarboxylate bridge [J].
Mrozinski, Jerzy ;
Bienko, Alina ;
Kopel, Pavel ;
Langer, Vratislav .
INORGANICA CHIMICA ACTA, 2008, 361 (12-13) :3723-3729
[33]   Synthesis, structure, magnetic and electrocatalytic properties of a dinuclear triazendio-copper(II) complex [J].
Yang, Hao ;
Du, Juan ;
Wang, Chun-Li ;
Xie, Ze-Hao ;
Zhan, Shu-Zhong .
INORGANIC AND NANO-METAL CHEMISTRY, 2023, 53 (07) :699-707
[34]   Synthesis, crystal structure, magnetic, photoluminescence and antibacterial properties of dinuclear Copper(II) complex [J].
Soltani, Sajjad ;
Akhbari, Kamran ;
White, Jonathan .
JOURNAL OF MOLECULAR STRUCTURE, 2020, 1214
[35]   Structure and Magnetic Properties of a Triply Oxygen. Bridged Dinuclear Ni(II) Complex [J].
Z Natur J Chem Sci, 8 (1132)
[36]   Structure and magnetic properties of a triply oxygen. Bridged dinuclear Ni(II) complex [J].
Elerman, Y ;
Kabak, M ;
Svoboda, I ;
Fuess, H ;
Griesar, K ;
Haase, W .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (08) :1132-1136
[37]   Structure, spectroscopic, and magnetic properties of copper(II) dinuclear complex with μ-hydroxo and μ-pyrazolato bridges [J].
Zareba, M ;
Drabent, K ;
Ciunik, Z ;
Wolowiec, S .
INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (01) :82-85
[38]   NEW DINUCLEATING LIGAND, N,N'-ETHYLENEBIS(3-CARBOXYSALICYLAMINE), AND ITS DINUCLEAR COPPER(II) AND NICKEL(II) COMPLEXES [J].
OKAWA, H ;
KOGAWA, K ;
HANDA, M ;
MATSUMOTO, N ;
KIDA, S .
CHEMISTRY LETTERS, 1988, (06) :1079-1080
[39]   OBSERVATIONS ON THE STRUCTURE AND MAGNETIC-PROPERTIES OF DINUCLEAR COPPER(II) COMPLEXES DERIVED FROM FLEXIBLE DINUCLEATING SCHIFF-BASE LIGANDS [J].
ADAMS, H ;
BAILEY, NA ;
FENTON, DE ;
MOODY, R .
INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1987, 135 (01) :L1-L3
[40]   Crystal structure and magnetic properties of a copper(II)-vanadium(IV) complex of an 'open-ended' dinucleating ligand [J].
Hazell, A ;
McKenzie, CJ ;
Moubaraki, B ;
Murray, KS .
ACTA CHEMICA SCANDINAVICA, 1997, 51 (04) :470-475
12345