Double metallation of a molecular tweezers with chromium and visible light-induced metal transfer into the cavity

被引：2

作者：

Catellani, M

Baroni, F

Bocelli, G

Ghelli, S

机构：

[1] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy

[2] CNR, Ctr Studio Strutturist Diffrattometr, I-43100 Parma, Italy

[3] Univ Modena, Dipartimento Chim, I-41100 Modena, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 583卷 / 1-2期

关键词：

chromium carbonyl; molecular tweezers; visible light; x-ray diffraction;

D O I：

10.1016/S0022-328X(99)00115-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

cis,exo-2-Phenyl-3-(2-E-phenylethenyl)norbornane reacts with Cr(CO)(6) to give mainly a bis-arene tricarbonylchromium complex. Under the influence of visible light, the latter undergoes conversion from externally to internally arene-bonded chromium carbonyl. with carbonyl displacement by the double bond, to form an eta(6),eta(2) metal-coordinated complex. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：106 / 110

页数：5

共 14 条

[1] BELLETTI D, 1995, 195 CTR STUD STRUTT
[2] BOCHMANN M, 1992, ANGEW CHEM INT EDIT, V31, P1181, DOI 10.1002/anie.199211811
[3] A NEW PALLADIUM CATALYZED SYNTHESIS OF CIS,EXO-2,3-DIARYLSUBSTITUTED BICYCLO[2.2.1]HEPTANES OR BICYCLO[2.2.1]HEPT-2-ENES
CATELLANI, M
CHIUSOLI, GP
CONCARI, S
[J]. TETRAHEDRON, 1989, 45 (16) : 5263 - 5268
[4] MOLECULAR TWEEZERS - SIMPLE-MODEL OF BIFUNCTIONAL INTERCALATION
CHEN, CW
WHITLOCK, HW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (15) : 4921 - 4922
[5] GLUZINSKI P, 1989, XRAY SET PROGRAMS XR
[6] Mahaffy C.A.L., 1979, Inorganic Syntheses, P154
[7] TRICARBONYLCHROMIUM(0) COMPLEXES OF 1,3,5-TRIPHENYLBENZENE - AN X-RAY CRYSTALLOGRAPHIC AND HIGH-FIELD NMR SPECTROSCOPIC STUDY
MAILVAGANAM, B
MCCARRY, BE
SAYER, BG
PERRIER, RE
FAGGIANI, R
MCGLINCHEY, MJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 335 (02) : 213 - 227
[8] SYNTHESIS AND SPECTRAL STUDY OF CHELATE ALKENYLARENEDICARBONYL COMPLEXES OF CR,MO AND W
NESMEYANOV, AN
RYBINSKAYA, MI
KRIVYKH, VV
PETROVSKII, PV
KAGANOVICH, VS
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 162 (03) : 323 - 342
[9] SYNTHESIS OF OPTICALLY-ACTIVE MACROMOLECULES USING METALLOCENE CATALYSTS
OKUDA, J
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (01): : 47 - 48
[10] SHELDRICK GH, 1993, SHELX93 PROGRAM CRYS

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