Enhanced Capacitance of Microwave-assisted Functionalized Ordered Mesopourous Carbon for Supercapacitors

被引：6

作者：

Portales-Martinez, B. ^{[1
]}

Gonzalez-Huerta, R. G. ^{[2
]}

Dominguez-Esquivel, J. M. ^{[3
]}

Cortes-Escobedo, C. A. ^{[1
]}

机构：

[1] IPN, Ctr Invest & Innovac Tecnol, Mexico City 02250, DF, Mexico

[2] IPN, Escuela Super Ingn Quim, Unidad Profes Adolfo Lopez Mateos, Lab Electrocatalisis, Mexico City 07738, DF, Mexico

[3] Inst Mexicano Petr, Mexico City 07730, DF, Mexico

来源：

JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS | 2012年 / 15卷 / 03期

关键词：

Ordered mesoporous carbon; functional isation; capacitance; supercapacitors; EDLC; RAY PHOTOELECTRON-SPECTROSCOPY; MESOPOROUS CARBON; SURFACE; CATALYST; SILICA; SBA-15; XPS;

D O I：

10.14447/jnmes.v15i3.66

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemical capacitance for a double layer of ordered mesoporous carbon (OMC) nanofibers funCtionalized under differing conditions is presented. OMC nanofibers were prepared using the molding method from SBA-15 and sucrose. Functionalisation was performed using varying HNO3 concentrations at 110 degrees C and 120 degrees C assisted by microwave radiation over 3 minutes. The transmission electron micrographs of the resulting fibers are reported. The capacitance, surface area and functional groups as functions of the acidity and heat treatment were analysed via cyclic voltammetry, nitrogen adsorption-desorption, and X-ray photoelectron spectroscopy, respectively. Ordered nanofibers treated with 7.7 M HNO3 at 110 degrees C exhibited the highest capacitance.

引用

页码：203 / 209

页数：7

共 31 条

[21] Physical and electrochemical characterization of hydrous ruthenium oxide/ordered mesoporous carbon composites as supercapacitor [J].

Li, Hongfang ;

Wang, Ruoding ;

Cao, Rong .

MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 111 (1-3) :32-38

[22] Preparation, structural characterization, and electrochemical properties of chemically modified mesoporous carbon [J].

Li, Hongfang ;

Xi, Hong' an ;

Zhu, Sumin ;

Wen, Zhaoyin ;

Wang, Ruoding .

MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 96 (1-3) :357-362

[23] A simplified preparation of mesoporous carbon and the examination of the carbon accessibility for electric double layer formation [J].

Liu, HY ;

Wang, KP ;

Teng, HS .

CARBON, 2005, 43 (03) :559-566

[24] Molecular level dispersed Pd clusters in the carbon walls of ordered mesoporous carbon as a highly selective alcohol oxidation catalyst [J].

Lu, An-Hui ;

Li, Wen-Cui ;

Hou, Zhenshan ;

Schueth, Ferdi .

CHEMICAL COMMUNICATIONS, 2007, (10) :1038-1040

[25] Fluorination of carbon blacks: An X-ray photoelectron spectroscopy study .1. A literature review of XPS studies of fluorinated carbons. XPS investigation of some reference compounds [J].

Nanse, G ;

Papirer, E ;

Fioux, P ;

Moguet, F ;

Tressaud, A .

CARBON, 1997, 35 (02) :175-194

[26] Carbon Nanotubes for Supercapacitor [J].

Pan, Hui ;

Li, Jianyi ;

Feng, Yuan Ping .

NANOSCALE RESEARCH LETTERS, 2010, 5 (03) :654-668

[27] DATA-ANALYSIS TECHNIQUES IN X-RAY PHOTO-ELECTRON SPECTROSCOPY [J].

PROCTOR, A ;

SHERWOOD, PMA .

ANALYTICAL CHEMISTRY, 1982, 54 (01) :13-19

[28] Synthesis and Electrochemical Property of Boron-Doped Mesoporous Carbon in Supercapacitor [J].

Wang, Da-Wei ;

Li, Feng ;

Chen, Zhi-Gang ;

Lu, Gao Qing ;

Cheng, Hui-Ming .

CHEMISTRY OF MATERIALS, 2008, 20 (22) :7195-7200

[29]

Watts J.F., 2003, An introduction to surface analysis by XPS and AES

[30] Superior electric double layer capacitors using ordered mesoporous carbons [J].

Xing, W ;

Qiao, SZ ;

Ding, RG ;

Li, F ;

Lu, GQ ;

Yan, ZF ;

Cheng, HM .

CARBON, 2006, 44 (02) :216-224

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