Enhanced Capacitance of Microwave-assisted Functionalized Ordered Mesopourous Carbon for Supercapacitors

被引:6
作者
Portales-Martinez, B. [1 ]
Gonzalez-Huerta, R. G. [2 ]
Dominguez-Esquivel, J. M. [3 ]
Cortes-Escobedo, C. A. [1 ]
机构
[1] IPN, Ctr Invest & Innovac Tecnol, Mexico City 02250, DF, Mexico
[2] IPN, Escuela Super Ingn Quim, Unidad Profes Adolfo Lopez Mateos, Lab Electrocatalisis, Mexico City 07738, DF, Mexico
[3] Inst Mexicano Petr, Mexico City 07730, DF, Mexico
关键词
Ordered mesoporous carbon; functional isation; capacitance; supercapacitors; EDLC; RAY PHOTOELECTRON-SPECTROSCOPY; MESOPOROUS CARBON; SURFACE; CATALYST; SILICA; SBA-15; XPS;
D O I
10.14447/jnmes.v15i3.66
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The electrochemical capacitance for a double layer of ordered mesoporous carbon (OMC) nanofibers funCtionalized under differing conditions is presented. OMC nanofibers were prepared using the molding method from SBA-15 and sucrose. Functionalisation was performed using varying HNO3 concentrations at 110 degrees C and 120 degrees C assisted by microwave radiation over 3 minutes. The transmission electron micrographs of the resulting fibers are reported. The capacitance, surface area and functional groups as functions of the acidity and heat treatment were analysed via cyclic voltammetry, nitrogen adsorption-desorption, and X-ray photoelectron spectroscopy, respectively. Ordered nanofibers treated with 7.7 M HNO3 at 110 degrees C exhibited the highest capacitance.
引用
收藏
页码:203 / 209
页数:7
相关论文
共 31 条
  • [1] Work functions and surface functional groups of multiwall carbon nanotubes
    Ago, H
    Kugler, T
    Cacialli, F
    Salaneck, WR
    Shaffer, MSP
    Windle, AH
    Friend, RH
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (38): : 8116 - 8121
  • [2] [Anonymous], 1999, ELECTROCHEMICAL SUPE
  • [3] Bazula P.A., 2008, MICROPOR MESOPOR MAT, V108, P266
  • [4] PRIMARY AND SECONDARY OXYGEN-INDUCED C1S BINDING-ENERGY SHIFTS IN X-RAY PHOTOELECTRON-SPECTROSCOPY OF POLYMERS
    BRIGGS, D
    BEAMSON, G
    [J]. ANALYTICAL CHEMISTRY, 1992, 64 (15) : 1729 - 1736
  • [5] Chmiola J, 2006, SCIENCE, V313, P1760, DOI 10.1126/science/1132195
  • [6] MnO2-embedded-in-mesoporous-carbon-wall structure for use as electrochemical capacitors
    Dong, XP
    Shen, WH
    Gu, JL
    Xiong, LM
    Zhu, YF
    Li, Z
    Shi, JL
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (12) : 6015 - 6019
  • [7] Templated mesoporous carbons for supercapacitor application
    Fuertes, AB
    Lota, G
    Centeno, TA
    Frackowiak, E
    [J]. ELECTROCHIMICA ACTA, 2005, 50 (14) : 2799 - 2805
  • [8] Oxygen reduction in acid media by a RuxFeySez(CO)n cluster catalyst dispersed on a glassy carbon-supported Nafion film
    González-Cruz, R
    Solorza-Feria, O
    [J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2003, 7 (05) : 289 - 295
  • [9] Effect of pore size distribution of coal-based activated carbons on double layer capacitance
    Gryglewicz, G
    Machnikowski, J
    Lorenc-Grabowska, E
    Lota, G
    Frackowiak, E
    [J]. ELECTROCHIMICA ACTA, 2005, 50 (05) : 1197 - 1206
  • [10] Surface-modified carbons as platinum catalyst support for PEM fuel cells
    Guha, Abhishek
    Lu, Weijie
    Zawodzinski, Thomas A., Jr.
    Schiraldi, David A.
    [J]. CARBON, 2007, 45 (07) : 1506 - 1517