Evaluating oxygen diffusion, surface exchange and oxygen semi-permeation in Ln2NiO4+δ membranes (Ln = La, Pr and Nd)

被引：31

作者：

Geffroy, P. -M. ^{[1
]}

Reichmann, M. ^{[1
,2
]}

Chartier, T. ^{[1
]}

Bassat, J. -M. ^{[3
]}

Grenier, J. -C. ^{[3
]}

机构：

[1] Univ Limoges, SPCTS, CNRS, ENSCI,CEC, F-87068 Limoges, France

[2] ADEME, F-49004 Angers 1, France

[3] Univ Bordeaux, CNRS, ICMCB, F-33608 Pessac, France

来源：

JOURNAL OF MEMBRANE SCIENCE | 2014年 / 451卷

关键词：

Oxygen diffusion; Oxygen surface exchange; Oxygen semi-permeation; Lanthanum nickelate; TRANSPORT-PROPERTIES; PEROVSKITE; MICROSTRUCTURE; CONDUCTIVITY; PERMEABILITY;

D O I：

10.1016/j.memsci.2013.08.035

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

To clearly identify the rate determining step (rd.s.) in the oxygen semi-permeation of dense Ln(2)NiO4+delta, membranes (with Ln=La, Pr and Nd), a specific apparatus was designed to measure the oxygen semi-permeation flux and activity gradient at both membrane surfaces. From these measurements, the coefficients for the oxygen diffusion and surface exchange at both membrane surfaces were determined. Their values were compared to the values reported in the literature for similar membrane materials. We concluded that the oxygen flux through these membranes was limited by the oxygen surface exchange at the oxygen-lean face and not oxygen volume diffusion, as previously claimed. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：234 / 242

页数：9

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