NPAM-assisted rapid synthesis of BiOBr ultrathin hierarchical clusters for efficient photocatalytic degradation of RhB and ciprofloxacin

被引:0
作者
Duo, Fangfang [1 ]
Zhang, Mingliang [2 ]
Chu, Liangliang [1 ]
Wang, Chubei [1 ]
Zhou, Jianwei [1 ]
机构
[1] Xinxiang Univ, Inst Energy & Fuel, Xinxiang 453003, Henan, Peoples R China
[2] Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China
关键词
Photocatalysis; BiOBr; ultrathin hierarchical cluster; Rhodamine B; ciprofloxacin; nonionic polyacrylamide; OXYGEN VACANCIES; BIOCL; NANOSHEETS; MICROSPHERES; OXIDATION;
D O I
10.1007/s12034-020-02224-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nonionic polyacrylamide (NPAM) bismuth bromoxide (BiOBr) ultrathin hierarchical clusters have been prepared by a rapid solvothermal synthesis route. The formation mechanism of the NPAM-BiOBr ultrathin hierarchical clusters was based on the strong bridging role of NPAM between the bismuthyl nitrate (BiONO3) particles and subsequently results in tight junctions between BiOBr nanosheets. The structure, morphology and optical properties of the prepared samples were characterized by X-ray diffraction, Raman spectra, scanning electron microscopy, diffuse reflectance spectroscopy and photoluminescence. The photocatalytic performance of NPAM-BiOBr was evaluated by the degradation of Rhodamine B (RhB) and ciprofloxacin. The photocatalytic efficiency increased by 2.1 and 2.5 times of NPAM-BiOBr for RhB and ciprofloxacin decomposition, respectively. The enhanced photocatalytic activity of NPAM-BiOBr was attributed to the increased light absorption capacity and lower recombination rate of the photo-generated electron and hole pairs.
引用
收藏
页数:7
相关论文
共 31 条
[1]  
Alex M, 2016, CHEM MAT, V28, P1980, DOI [10.1021/acs.chemmater.6b00349, DOI 10.1021/ACS.CHEMMATER.6B00349]
[2]   Graphitic carbon nitride nanosheets anchored with BiOBr and carbon dots: Exceptional visible-light-driven photocatalytic performances for oxidation and reduction reactions [J].
Asadzadeh-Khaneghah, Soheila ;
Habibi-Yangjeh, Aziz ;
Nakata, Kazuya .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2018, 530 :642-657
[3]   Facet-Engineered Surface and Interface Design of Photocatalytic Materials [J].
Bai, Song ;
Wang, Lili ;
Li, Zhengquan ;
Xiong, Yujie .
ADVANCED SCIENCE, 2017, 4 (01)
[4]   Engineering of ZnO nanostructures for efficient solar photocatalysis [J].
Das, Abinash ;
Malakar, P. ;
Nair, Ranjith G. .
MATERIALS LETTERS, 2018, 219 :76-80
[5]   Nitrogen-Doped Carbon Quantum Dots/BiOBr Ultrathin Nanosheets: In Situ Strong Coupling and Improved Molecular Oxygen Activation Ability under Visible Light Irradiation [J].
Di, Jun ;
Xia, Jiexiang ;
Ji, Mengxia ;
Wang, Bin ;
Li, Xiaowei ;
Zhang, Qi ;
Chen, Zhigang ;
Li, Huaming .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (01) :136-146
[6]   Visible-light-induced charge transfer pathway and photocatalysis mechanism on Bi semimetal@defective BiOBr hierarchical microspheres [J].
Dong, Xing'an ;
Zhang, Wendong ;
Sun, Yanjuan ;
Li, Jieyuan ;
Cen, Wanglai ;
Cui, Zhihao ;
Huang, Hongwei ;
Dong, Fan .
JOURNAL OF CATALYSIS, 2018, 357 :41-50
[7]   Fast photocatalytic degradation of ciprofloxacin over Ce3+/Ce4+?induced BiOCl nanosheets and antibacterial activity elimination [J].
Duo, Fangfang ;
Zhang, Mingliang ;
Zhou, Jianwei ;
Wang, Chubei ;
Chu, Liangliang ;
Su, Xinmei .
MATERIALS RESEARCH EXPRESS, 2019, 6 (11)
[8]   Rapid synthesis of hierarchical BiOCl microspheres for efficient photocatalytic degradation of carbamazepine under simulated solar irradiation [J].
Gao, Xiaoya ;
Zhang, Xiaochao ;
Wang, Yawen ;
Peng, Shiqi ;
Yue, Bin ;
Fan, Caimei .
CHEMICAL ENGINEERING JOURNAL, 2015, 263 :419-426
[9]   Enhanced charge separation and increased oxygen vacancies of h-BN/OV-BiOCl for improved visible-light photocatalytic performance [J].
He, Wenhui ;
Wang, Yawen ;
Fan, Caimei ;
Wang, Yunfang ;
Zhang, Xiaochao ;
Liu, Jianxin ;
Li, Rui .
RSC ADVANCES, 2019, 9 (25) :14286-14295
[10]   Absorption of light dark matter in semiconductors [J].
Hochberg, Yonit ;
Lin, Tongyan ;
Zurek, Kathryn M. .
PHYSICAL REVIEW D, 2017, 95 (02)